Novel ferrocene modified P,N-ligands for enantioselective palladium-catalyzed allylic substituion reactions. | |
You SL(游书力) ; Hou XL(侯雪龙) ; Dai LX(戴立信) | |
刊名 | J. Organomet. Chem.
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2001 | |
卷号 | 637-639页码:762-766 |
ISSN号 | 0022-328X |
其他题名 | 新型二茂铁修饰的 P,N 配体及对映选择性钯催化烯丙基取代反应 |
通讯作者 | 侯雪龙 |
英文摘要 | Novel ferrocene modified P,N-ligands(R,R,Sp)-8and (S,S,Sp)-9 were synthesized conveniently from enantiopure cyclohexane diamine and (Sp)-2-phosphinoferrocenyl carboxylic acid. Theywere used as chiral ligands for palladium-catalyzed allylic substitutions of rac-1,3-diphenylprop-2-enyl acetate with dimethylmalonate and benzylamine (R,R,Sp)-8was found to be a better ligand containing matched chiralities (central chirality and planar chirality) and showed a higher enantioselectivity. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1016/S0022-328X(01)00911-1 |
语种 | 英语 |
公开日期 | 2013-02-19 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/15863] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | You SL,Hou XL,Dai LX. Novel ferrocene modified P,N-ligands for enantioselective palladium-catalyzed allylic substituion reactions.[J]. J. Organomet. Chem.,2001,637-639:762-766. |
APA | 游书力,侯雪龙,&戴立信.(2001).Novel ferrocene modified P,N-ligands for enantioselective palladium-catalyzed allylic substituion reactions..J. Organomet. Chem.,637-639,762-766. |
MLA | 游书力,et al."Novel ferrocene modified P,N-ligands for enantioselective palladium-catalyzed allylic substituion reactions.".J. Organomet. Chem. 637-639(2001):762-766. |
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