Novel ferrocene modified P,N-ligands for enantioselective palladium-catalyzed allylic substituion reactions.
You SL(游书力) ; Hou XL(侯雪龙) ; Dai LX(戴立信)
刊名J. Organomet. Chem.
2001
卷号637-639页码:762-766
ISSN号0022-328X
其他题名新型二茂铁修饰的 P,N 配体及对映选择性钯催化烯丙基取代反应
通讯作者侯雪龙
英文摘要Novel ferrocene modified P,N-ligands(R,R,Sp)-8and (S,S,Sp)-9 were synthesized conveniently from enantiopure cyclohexane diamine and (Sp)-2-phosphinoferrocenyl carboxylic acid. Theywere used as chiral ligands for palladium-catalyzed allylic substitutions of rac-1,3-diphenylprop-2-enyl acetate with dimethylmalonate and benzylamine (R,R,Sp)-8was found to be a better ligand containing matched chiralities (central chirality and planar chirality) and showed a higher enantioselectivity.
学科主题金属有机化学
收录类别SCI
原文出处http://dx.doi.org/10.1016/S0022-328X(01)00911-1
语种英语
公开日期2013-02-19
内容类型期刊论文
源URL[http://202.127.28.38/handle/331003/15863]  
专题上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式
GB/T 7714
You SL,Hou XL,Dai LX. Novel ferrocene modified P,N-ligands for enantioselective palladium-catalyzed allylic substituion reactions.[J]. J. Organomet. Chem.,2001,637-639:762-766.
APA 游书力,侯雪龙,&戴立信.(2001).Novel ferrocene modified P,N-ligands for enantioselective palladium-catalyzed allylic substituion reactions..J. Organomet. Chem.,637-639,762-766.
MLA 游书力,et al."Novel ferrocene modified P,N-ligands for enantioselective palladium-catalyzed allylic substituion reactions.".J. Organomet. Chem. 637-639(2001):762-766.
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