Assembly of the highest connectivity Wells-Dawson polyoxometalate coordination polymer: the use of organic ligand flexibility

	Assembly of the highest connectivity Wells-Dawson polyoxometalate coordination polymer: the use of organic ligand flexibility
	Tian AX ; Ying J ; Peng J ; Sha JQ ; Han ZG ; Ma JF ; Su ZM ; Hu NH ; Jia HQ
刊名	inorganic chemistry
	2008
卷号	47 期号:8 页码:3274-3283
关键词	CRYSTAL-STRUCTURE HYDROTHERMAL SYNTHESIS ELECTROCHEMICAL PROPERTIES MAGNETIC-PROPERTIES HYBRID COMPOUNDS HELICAL CHAINS BUILT-UP FRAMEWORK CLUSTERS COMPLEXES
ISSN号	0020-1669
通讯作者	peng j
中文摘要	through tuning the length of flexible bis(triazole) ligands and different metal ion coordination geometries, four wells-dawson polyoxoanion-based hybrid compounds, [cu-6(btp)(3)(p2w18o62)] center dot 3h(2)o (1) (btp = 1,3-bis(1,2,4-triazol-1-yl)propane), [cu-6(btb)(3)((p2w18o62) center dot 2h(2)o (2), [cu-3(btb)(6)(p2w18o62)] center dot 6h(2)o (btb = 1,4-bis(1,2,4-triazol-1-yl)butane) (3), and [cu-3(btx)(5.5)((p2w18o62) center dot 4h(2)o (btx = 1,6-bis(1,2,4-triazol-1-yl)hexane) (4), were synthesized and structurally characterized. in compound 1, the metal-organic motif exhibits a ladder-like chain, which is further fused by the ennead-dentate [p2w18o62](6-) anions to construct a 3d structure. in compound 2, the metal-organic motif exhibits an interesting cu-btb grid layer, and the ennead-dentate polyoxoanions are sandwiched by two cu-btb layers to construct a 3d structure
收录类别	SCI
语种	英语
WOS记录号	WOS:000254902000051
公开日期	2010-04-14
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/9769]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Tian AX,Ying J,Peng J,et al. Assembly of the highest connectivity Wells-Dawson polyoxometalate coordination polymer: the use of organic ligand flexibility[J]. inorganic chemistry ,2008,47(8):3274-3283.
APA	Tian AX.,Ying J.,Peng J.,Sha JQ.,Han ZG.,...&Jia HQ.(2008).Assembly of the highest connectivity Wells-Dawson polyoxometalate coordination polymer: the use of organic ligand flexibility.inorganic chemistry ,47(8),3274-3283.
MLA	Tian AX,et al."Assembly of the highest connectivity Wells-Dawson polyoxometalate coordination polymer: the use of organic ligand flexibility".inorganic chemistry 47.8(2008):3274-3283.