全钒液流电池铂氢微型参比电极体系的构筑与性能

CORC > 厦门大学 > 2015年第21卷

	全钒液流电池铂氢微型参比电极体系的构筑与性能; A Platinum-Hydrogen Reference Micro-Electrode for All Vanadium Redox Flow Battery
	林志彬 ; 董燕青 ; 郑明森 ; 董全峰 ; LIN Zhi-bin ; DONG Yan-qing ; ZHENG Ming-sen ; DONG Quan-feng
刊名	http://electrochem.xmu.edu.cn/CN/abstract/abstract10150.shtml
	2015-04-28
关键词	参比电极全钒液流电池 PVP-PES隔膜 reference electrode all vanadium redox flow batteries application
英文摘要	铂丝电极表面上电沉积一层金属钯，用阴离子交换隔膜材料封装，制得铂氢微型参比电极，工艺简单、稳定性高. 将该微型参比电极应用于全钒储能电池性能研究，可内置于电池多孔电极内部，监测电池正负极充放电性能. 结果显示，电池容量衰减主要归因于电解液中的活性物质V(IV)的逐渐减少及V(V)的积累导致正负极活性物质不平衡.; A platinum-hydrogen reference micro-electrode was made with electroplating Pd on the surface of Pt wire and then coating anion membrane material. This reference electrode was built-in the porous electrode of the all vanadium redox flow batteries (VRFB), and monitored the charging /discharging and self-discharging of the VRFB. The results indicated that the capacity fading of VRFB occurred due to the graduate reduction of V(IV) active species in the electrolyte and the accumulation of V(V) in the positive electrode, leading to nonequilibrium of active species between the positive and negative electrodes.; 作者联系地址：1. 厦门大学能源学院，福建厦门 361005；2. 厦门大学化学化工学院，福建厦门 361005; Author's Address: 1. College of Energy, Xiamen University, Xiamen 361005, Fujian, China; 2. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China; 通讯作者E-mail：qfdong@xmu.edu.cn
语种	中文
出版者	厦门大学《电化学》编辑部
内容类型	期刊论文
源URL	[http://dx.doi.org/10.13208/j.electrochem.141209]
专题	2015年第21卷
推荐引用方式 GB/T 7714	林志彬,董燕青,郑明森,等. 全钒液流电池铂氢微型参比电极体系的构筑与性能, A Platinum-Hydrogen Reference Micro-Electrode for All Vanadium Redox Flow Battery[J]. http://electrochem.xmu.edu.cn/CN/abstract/abstract10150.shtml,2015.
APA	林志彬.,董燕青.,郑明森.,董全峰.,LIN Zhi-bin.,...&DONG Quan-feng.(2015).全钒液流电池铂氢微型参比电极体系的构筑与性能.http://electrochem.xmu.edu.cn/CN/abstract/abstract10150.shtml.
MLA	林志彬,et al."全钒液流电池铂氢微型参比电极体系的构筑与性能".http://electrochem.xmu.edu.cn/CN/abstract/abstract10150.shtml (2015).