基于琼脂支撑的液/液界面上AgTCNQ的电化学合成

CORC > 厦门大学 > 2012年第18卷

	基于琼脂支撑的液/液界面上AgTCNQ的电化学合成; Electrochemical Synthesis of Silver-Tetracyanoquinodimethane Nanorods at Agar Supported Water/1,2-Dichloroethane Interface
	黄丽 ; 汪宜娴 ; MichaelV.Mirkin ; 任斌 ; 詹东平 ; Li Huang ; Yixian Wang ; Michael V. Mirkin ; Bin Ren ; Dongping Zhan
刊名	http://electrochem.xmu.edu.cn/CN/abstract/abstract9927.shtml
	2012-12-03
关键词	液/液界面银-四氰基对苯二醌二甲烷电化学合成纳米棒 liquid/liquid interface silver-tetracyanoquinodimethane electrochemical synthesis nanorods
英文摘要	具有高导电性和独特电学性质的金属有机络合物AgTCNQ是一种重要的电荷转移盐.本文采用琼脂作为胶凝剂构成水\|1,2-二氯乙烷液液界面；施加电压时银离子由水相穿过水凝胶进入有机相，与TCNQ-反应生成AgTCNQ纳米棒.结果表明液/液界面电化学方法为合成有机金属功能材料的有效途径.; Silver-tetracyanoquinodimethane (AgTCNQ) is an important charge transfer salt due to its high conductivity and other electronic properties. In this communication, we report the synthesis of AgTCNQ at the liquid/liquid interface. Agar was used as a gelling agent to support water/1,2-dichloroethane (DCE) interface. Silver ions were transferred from the hydrogel into DCE phase, where they combined with TCNQ- to form AgTCNQ nanorods. The developed method can provide a new route for synthesis of functional materials based on the electrochemistry at the liquid/liquid interface.; This work was supported by National Science Foundation of China (No. 20973142, No. 21061120456, and No. 21021002), National Basic Research Program of China (2011CB933700) and the National Science Foundation (CHE-1026582; MVM).; This work was supported by National Science Foundation of China (No. 20973142, No. 21061120456, and No. 21021002), National Basic Research Program of China (2011CB933700) and the National Science Foundation (CHE-1026582; MVM).; 作者联系地址：1. 厦门大学化学化工学院化学系, 福建厦门361005; 2. 厦门大学固体表面物理化学国家重点实验室, 福建厦门361005; 3. 纽约市立大学皇后学院化学与生物化学系袁美国纽约11367; Author's Address: 1. Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China; 2. State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, Fujian, China; 3. Department of Chemistry and Biochemistry, Queens College-CUNY, Flushing, New York 11367, USA; 通讯作者E-mail：dpzhan@xmu.edu.cn
语种	中文
出版者	厦门大学《电化学》编辑部
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/58534]
专题	2012年第18卷
推荐引用方式 GB/T 7714	黄丽,汪宜娴,MichaelV.Mirkin,等. 基于琼脂支撑的液/液界面上AgTCNQ的电化学合成, Electrochemical Synthesis of Silver-Tetracyanoquinodimethane Nanorods at Agar Supported Water/1,2-Dichloroethane Interface[J]. http://electrochem.xmu.edu.cn/CN/abstract/abstract9927.shtml,2012.
APA	黄丽.,汪宜娴.,MichaelV.Mirkin.,任斌.,詹东平.,...&Dongping Zhan.(2012).基于琼脂支撑的液/液界面上AgTCNQ的电化学合成.http://electrochem.xmu.edu.cn/CN/abstract/abstract9927.shtml.
MLA	黄丽,et al."基于琼脂支撑的液/液界面上AgTCNQ的电化学合成".http://electrochem.xmu.edu.cn/CN/abstract/abstract9927.shtml (2012).