(p-CH_3C_6H_4SO_3)_3Nd+DMF体系中电沉积钕-铁族合金膜; Electrodeposition of Neodymium_Iron Group Alloy Films in( p _CH 3C 6H 4SO 3) 3Nd+DMF System | |
Liu Peng ; Tong Yexiang ; Yang Qiqin ; Yang Yansheng | |
刊名 | http://electrochem.xmu.edu.cn/CN/abstract/abstract9440.shtml |
1999-02-28 | |
关键词 | Neodymium p _toluenesulfonate Alloy films of neodymium_iron group Electrodeposition Organic electrolytes |
英文摘要 | 本世纪30年代Audreith等人基于分离稀土元素的目的,在某些有机溶剂电解液中用汞阴极电沉积了个别的稀土汞齐[1].1954年Moeler等在乙二胺中电沉积了Y、La和Nd(稀土含量只有50%左右)[2].随着电子和信息技术的发展,稀土合金功能薄膜...; Neodymium p _toluenesulfonate was prepared and applied to the electrodepositon of neodymium_iron group alloy films. This salt has high solubility in DMF and can be dehydrated easily. Cyclic voltammograms of Pt electrode in ( p _CH 3C 6H 4SO 3) 3Nd+MCl 2(M=Fe,Co,Ni)+DMF indicated that the neodymiun_iron group alloys can be elcetrodeposited from this medium, the Nd_Fe,Nd_Co and Nd_Ni films were obtained by electrolysis at constant potential. The Nd_Fe,Nd_Co and Nd_Ni films are amorphous in which the rare earth contents are in the range of 15 at%~60 at% as analyzed by XRD and EDS. The Nd content in the deposited film increases with the shift of cathode potential to the negative direction. The deposited Nd_Co film has good soft magnetic properites and its crystallization temperature was determined as 468.3 ℃.; Author's Address: School of Chem. and Chem. Engin., Zhongshan University, Guangzhou 510275 |
语种 | 中文 |
出版者 | 厦门大学《电化学》编辑部 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/57477] |
专题 | 1999年第5卷 |
推荐引用方式 GB/T 7714 | Liu Peng,Tong Yexiang,Yang Qiqin,等. (p-CH_3C_6H_4SO_3)_3Nd+DMF体系中电沉积钕-铁族合金膜, Electrodeposition of Neodymium_Iron Group Alloy Films in( p _CH 3C 6H 4SO 3) 3Nd+DMF System[J]. http://electrochem.xmu.edu.cn/CN/abstract/abstract9440.shtml,1999. |
APA | Liu Peng,Tong Yexiang,Yang Qiqin,&Yang Yansheng.(1999).(p-CH_3C_6H_4SO_3)_3Nd+DMF体系中电沉积钕-铁族合金膜.http://electrochem.xmu.edu.cn/CN/abstract/abstract9440.shtml. |
MLA | Liu Peng,et al."(p-CH_3C_6H_4SO_3)_3Nd+DMF体系中电沉积钕-铁族合金膜".http://electrochem.xmu.edu.cn/CN/abstract/abstract9440.shtml (1999). |
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