铅锑电极上PbO_2生长过程的阻抗跟踪法研究; Study on the Growth Process of Lead Dioxide on Lead-Antimony Electrodes by Impedance Tracing Method | |
韦国林 ; 杨鸿兴 ; 王家荣 ; Wei Guolin ; Yang Hongxin ; Wang Jiarong | |
刊名 | http://electrochem.xmu.edu.cn/CN/abstract/abstract9641.shtml
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1996-08-28 | |
关键词 | Impedance tracing Lead-antimony electrode Lead-dioxide electrode Electrocrystallization |
英文摘要 | 铅锑电极上PbO_2生长过程的阻抗跟踪法研究韦国林,杨鸿兴,王家荣(上海大学嘉定校区化学系,上海,201800)利用交流阻抗技术研究Pb/H2SO4体系中电化学过程,通常采用某一等效电路,并对所得的多频率阻抗频谱进行拟合处理,由此获得相关电化学信息。?..; The growth process of PbO2 formed by the oxidation of PbSO4 in the anodic film on lead-(1,3,5,7)wt%antimony electrodes was investigated with impedance tracing method of single frequency and the current-time transient method. The influence of antimony on this process was studied.The simulation curves obtained for capacity-time transients fit the experimental results very well.It has been shown that the mentioned growth process is a two-dimentional instantaneous nucleation and growth process,Antimony will inhibit the growth of PbO2 nucleus but enhance its nucleation.; 作者联系地址:上海大学嘉定校区化学系; Author's Address: Department of Chemistry,Shanghai University,Jiading Campus,Shanghai,201800 |
语种 | 中文 |
出版者 | 厦门大学《电化学》编辑部 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/57228] ![]() |
专题 | 1996年第2卷 |
推荐引用方式 GB/T 7714 | 韦国林,杨鸿兴,王家荣,等. 铅锑电极上PbO_2生长过程的阻抗跟踪法研究, Study on the Growth Process of Lead Dioxide on Lead-Antimony Electrodes by Impedance Tracing Method[J]. http://electrochem.xmu.edu.cn/CN/abstract/abstract9641.shtml,1996. |
APA | 韦国林,杨鸿兴,王家荣,Wei Guolin,Yang Hongxin,&Wang Jiarong.(1996).铅锑电极上PbO_2生长过程的阻抗跟踪法研究.http://electrochem.xmu.edu.cn/CN/abstract/abstract9641.shtml. |
MLA | 韦国林,et al."铅锑电极上PbO_2生长过程的阻抗跟踪法研究".http://electrochem.xmu.edu.cn/CN/abstract/abstract9641.shtml (1996). |
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