NMR and theoretical study on the coordination interaction between peroxovanadium( V) complexes and 5-amino-1,10-phenanthroline

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	NMR and theoretical study on the coordination interaction between peroxovanadium( V) complexes and 5-amino-1,10-phenanthroline
	Yu, Xianyong ; Deng, Lin ; Tao, Hongwen ; Jiang, Bingfei ; Li, Xiaofang ; Yu XY(于贤勇)
刊名	http://dx.doi.org/10.1080/00958972.2014.880783
	2014-01-17
关键词	AMINO-ACIDS VANADIUM COMPOUNDS LIGANDS 1,10-PHENANTHROLINE DNA DIPEROXOVANADATE SUBSTITUTION POTENTIALS CONTINUUM ENERGIES
英文摘要	Hunan Provincial Natural Science Foundation of China [14JJ7049]; Scientific Research Fund of Hunan Provincial Education Department [12K101]; State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University [201309]; Aid program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province; To understand the coordination modes and the solution structure of 5-amino-1,10-phenanthroline (5-NH2-phen), the coordination reaction between peroxovanadium(V) complex [OV(O-2)(2)(D2O)](-)/[OV(O-2)(2)(HOD)](-) and 5-NH2-phen has been investigated by multinuclear (H-1, C-13, and V-51) magnetic resonance with variable temperature NMR, COSY, and HSQC. The experimental results indicate a pair of isomers in solution, which are attributed to different coordination modes between vanadium and 5-NH2-phen. The solution structures of these newly formed peroxovanadate species were proposed based on experimental NMR information and confirmed by theoretical calculations. Moreover, the results of density functional calculations indicate that solvation plays an important role in these interactions.
语种	英语
出版者	TAYLOR & FRANCIS LTD
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/92039]
专题	物理技术－已发表论文
推荐引用方式 GB/T 7714	Yu, Xianyong,Deng, Lin,Tao, Hongwen,et al. NMR and theoretical study on the coordination interaction between peroxovanadium( V) complexes and 5-amino-1,10-phenanthroline[J]. http://dx.doi.org/10.1080/00958972.2014.880783,2014.
APA	Yu, Xianyong,Deng, Lin,Tao, Hongwen,Jiang, Bingfei,Li, Xiaofang,&于贤勇.(2014).NMR and theoretical study on the coordination interaction between peroxovanadium( V) complexes and 5-amino-1,10-phenanthroline.http://dx.doi.org/10.1080/00958972.2014.880783.
MLA	Yu, Xianyong,et al."NMR and theoretical study on the coordination interaction between peroxovanadium( V) complexes and 5-amino-1,10-phenanthroline".http://dx.doi.org/10.1080/00958972.2014.880783 (2014).