Concise synthesis of novel practical sulfamide-amine alcohols for the enantioselective addition of diethylzinc to aldehydes

	Concise synthesis of novel practical sulfamide-amine alcohols for the enantioselective addition of diethylzinc to aldehydes
	Mao, JC ; Wan, BS ; Wang, RL ; Wu, F ; Lu, SW
刊名	journal of organic chemistry
	2004-12-24
卷号	69 期号:26 页码:9123-9127
产权排序	1;1
英文摘要	novel sulfamide-amine alcohol ligands were designed using a grafting strategy and synthesized from readily available starting materials via a simple, efficient method. the key features of these ligands for the asymmetric addition of diethylzinc to aldehydes included stability, enhanced effectiveness without using ti((opr)-pr-i)(4), suitability for a variety of aldehydes, the ability to operate at room temperature, and selectability to afford either absolute configuration products with enantiomeric excess up to >99%.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	chiral nitrogen activators ; diels-alder reactions ; achiral ligands ; titanium(iv) complexes ; asymmetric activation ; organozinc reagents ; dialkylzinc addition ; atom economy ; catalysts ; benzaldehyde
收录类别	SCI ; IC ; CCR
原文出处	true
语种	英语
WOS记录号	WOS:000225919800016
公开日期	2010-11-30
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/81891]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Mao, JC,Wan, BS,Wang, RL,et al. Concise synthesis of novel practical sulfamide-amine alcohols for the enantioselective addition of diethylzinc to aldehydes[J]. journal of organic chemistry,2004,69(26):9123-9127.
APA	Mao, JC,Wan, BS,Wang, RL,Wu, F,&Lu, SW.(2004).Concise synthesis of novel practical sulfamide-amine alcohols for the enantioselective addition of diethylzinc to aldehydes.journal of organic chemistry,69(26),9123-9127.
MLA	Mao, JC,et al."Concise synthesis of novel practical sulfamide-amine alcohols for the enantioselective addition of diethylzinc to aldehydes".journal of organic chemistry 69.26(2004):9123-9127.