Electrosynthesis of Copper-Tetracyanoquinodimethane Based on the Coupling Charge Transfer across Water/1,2-Dichloroethane Interface

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	Electrosynthesis of Copper-Tetracyanoquinodimethane Based on the Coupling Charge Transfer across Water/1,2-Dichloroethane Interface
	Huang, Li ; Li, Pei ; Pamphile, Ndagijimana ; Tian, Zhong-Qun ; Zhan, Dongping ; Tian ZQ(田中群) ; Zhan DP(詹东平)
刊名	http://dx.doi.org/10.1016/j.electacta.2014.04.102
	2014
关键词	Copper Electronic properties Field effect transistors Needles Organometallics Semiconductor devices Solutions
英文摘要	The organic salt Copper-Tetracyanoquinodimethane (CuTCNQ) is an important semiconductor used in electronics for field-effect transistors, switches and memory devices. Here we present a novel electrosynthetic method of CuTCNQ microneedles based on the coupling charge transfer across water/1,2- dichloroethane (W/1,2-DCE) interface. A HOPG electrode is covered by a small volume of 1,2-DCE solution, which is further covered by an aqueous solution to construct the W/1,2-DCE interface. When TCNQ in 1,2-DCE phase is reduced on HOPG, Cu2+ in the aqueous solution will transfer across the W/1,2-DCE interface in order to maintain the electric neutrality. Therein CuTCNQ microneedles are formed which have good solid-state electrochemical and electronic properties. This coupling charge transfer mechanism is valuable and broadens the applications of liquid/liquid interface in organic electrosynthesis. ? 2014 Elsevier Ltd.
语种	英语
出版者	Elsevier Ltd
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89854]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Huang, Li,Li, Pei,Pamphile, Ndagijimana,et al. Electrosynthesis of Copper-Tetracyanoquinodimethane Based on the Coupling Charge Transfer across Water/1,2-Dichloroethane Interface[J]. http://dx.doi.org/10.1016/j.electacta.2014.04.102,2014.
APA	Huang, Li.,Li, Pei.,Pamphile, Ndagijimana.,Tian, Zhong-Qun.,Zhan, Dongping.,...&詹东平.(2014).Electrosynthesis of Copper-Tetracyanoquinodimethane Based on the Coupling Charge Transfer across Water/1,2-Dichloroethane Interface.http://dx.doi.org/10.1016/j.electacta.2014.04.102.
MLA	Huang, Li,et al."Electrosynthesis of Copper-Tetracyanoquinodimethane Based on the Coupling Charge Transfer across Water/1,2-Dichloroethane Interface".http://dx.doi.org/10.1016/j.electacta.2014.04.102 (2014).