C-4 Cumulene and the Corresponding Air-Stable Radical Cation and Dication

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	C-4 Cumulene and the Corresponding Air-Stable Radical Cation and Dication
	Li, Yan ; Mondal, Kartik Chandra ; Samuel, Prinson P. ; Zhu, Hongping ; Orben, Claudia M. ; Panneerselvam, Saravanan ; Dittrich, Birger ; Schwederski, Brigitte ; Kaim, Wolfgang ; Mondal, Totan ; Koley, Debasis ; Roesky, Herbert W. ; Li Y(李彦) ; Zhu HP(朱红平)
刊名	http://dx.doi.org/10.1002/anie.201310975
	2014-04-14
关键词	ALKYL AMINO CARBENES COORDINATION CHEMISTRY MOLECULES CARBON IONS CARBODICARBENE BUTATRIENE SILICON(0) LIGANDS DONOR
英文摘要	Deutsche Forschungsgemeinschaft [RO 224/60-1]; CSIR; IISER-Kolkata; SERB [SR/FT/CS-72/2011]; China Scholarship Council [CSC/91027014]; A neutral C-4 cumulene 1 that includes a cyclic alkyl(amino) carbene (cAAC), its air-stable radical cation 1(.+), and dication 1(2+) have been synthesized. The redox property of 1(.+) was studied by cyclic voltammetry. EPR and theoretical calculations show that the unpaired electron in 1(.+) is mainly delocalized over the central C-4 backbone. The commercially available CBr4 is utilized as a source of dicarbon in the cumulene synthesis.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/89323]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Li, Yan,Mondal, Kartik Chandra,Samuel, Prinson P.,et al. C-4 Cumulene and the Corresponding Air-Stable Radical Cation and Dication[J]. http://dx.doi.org/10.1002/anie.201310975,2014.
APA	Li, Yan.,Mondal, Kartik Chandra.,Samuel, Prinson P..,Zhu, Hongping.,Orben, Claudia M..,...&朱红平.(2014).C-4 Cumulene and the Corresponding Air-Stable Radical Cation and Dication.http://dx.doi.org/10.1002/anie.201310975.
MLA	Li, Yan,et al."C-4 Cumulene and the Corresponding Air-Stable Radical Cation and Dication".http://dx.doi.org/10.1002/anie.201310975 (2014).