CLAVUDIOL-A AND CLAVIROLIDE-A, 2 MARINE DOLABELLANE DITERPENES FROM THE SOFT CORAL CLAVULARIA-VIRIDIS | |
SU, JY ; ZHONG, YL ; SHI, KL ; QI, C ; SNYDER, JK ; HU, SZ ; HUANG, YQ ; Hu SZ(胡盛志) | |
刊名 | http://dx.doi.org/10.1021/jo00007a019 |
1991-03-29 | |
关键词 | TRINOR-GUAIANE SESQUITERPENE C-13-H-1 SHIFT CORRELATION NATURAL-PRODUCTS PROSTANOIDS CLAVULONES DICTYOTA-DICHOTOMA CLAVIRIDENONE-A KOELLIKERI GAIMARD INFLATA QUOY |
英文摘要 | The structures of two new marine diterpenes, clavudiol A (1) and clavirolide A (2), isolated from the Pacific soft coral Clavularia viridis collected off the Xisha Islands in the South China Sea are reported. Particularly valuable in the structure assignments of these two natural products was the two-dimensional NMR FLOCK sequence for detection of long range heteronuclear (C-13, H-1) couplings, and the use of the QUANTA/CHARMm molecular modeling program to support the NMR conformational analysis. The absolute stereochemistry of 1 and 2 were established by circular dichroism, and the structure of 1 (relative stereochemistry) ultimately confirmed by X-ray crystallography. Both are members of the dolabellane class of diterpenes. |
语种 | 英语 |
出版者 | J ORG CHEM |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/88480] |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | SU, JY,ZHONG, YL,SHI, KL,et al. CLAVUDIOL-A AND CLAVIROLIDE-A, 2 MARINE DOLABELLANE DITERPENES FROM THE SOFT CORAL CLAVULARIA-VIRIDIS[J]. http://dx.doi.org/10.1021/jo00007a019,1991. |
APA | SU, JY.,ZHONG, YL.,SHI, KL.,QI, C.,SNYDER, JK.,...&胡盛志.(1991).CLAVUDIOL-A AND CLAVIROLIDE-A, 2 MARINE DOLABELLANE DITERPENES FROM THE SOFT CORAL CLAVULARIA-VIRIDIS.http://dx.doi.org/10.1021/jo00007a019. |
MLA | SU, JY,et al."CLAVUDIOL-A AND CLAVIROLIDE-A, 2 MARINE DOLABELLANE DITERPENES FROM THE SOFT CORAL CLAVULARIA-VIRIDIS".http://dx.doi.org/10.1021/jo00007a019 (1991). |
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