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CLAVUDIOL-A AND CLAVIROLIDE-A, 2 MARINE DOLABELLANE DITERPENES FROM THE SOFT CORAL CLAVULARIA-VIRIDIS
SU, JY ; ZHONG, YL ; SHI, KL ; QI, C ; SNYDER, JK ; HU, SZ ; HUANG, YQ ; Hu SZ(胡盛志)
刊名http://dx.doi.org/10.1021/jo00007a019
1991-03-29
关键词TRINOR-GUAIANE SESQUITERPENE C-13-H-1 SHIFT CORRELATION NATURAL-PRODUCTS PROSTANOIDS CLAVULONES DICTYOTA-DICHOTOMA CLAVIRIDENONE-A KOELLIKERI GAIMARD INFLATA QUOY
英文摘要The structures of two new marine diterpenes, clavudiol A (1) and clavirolide A (2), isolated from the Pacific soft coral Clavularia viridis collected off the Xisha Islands in the South China Sea are reported. Particularly valuable in the structure assignments of these two natural products was the two-dimensional NMR FLOCK sequence for detection of long range heteronuclear (C-13, H-1) couplings, and the use of the QUANTA/CHARMm molecular modeling program to support the NMR conformational analysis. The absolute stereochemistry of 1 and 2 were established by circular dichroism, and the structure of 1 (relative stereochemistry) ultimately confirmed by X-ray crystallography. Both are members of the dolabellane class of diterpenes.
语种英语
出版者J ORG CHEM
内容类型期刊论文
源URL[http://dspace.xmu.edu.cn/handle/2288/88480]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
SU, JY,ZHONG, YL,SHI, KL,et al. CLAVUDIOL-A AND CLAVIROLIDE-A, 2 MARINE DOLABELLANE DITERPENES FROM THE SOFT CORAL CLAVULARIA-VIRIDIS[J]. http://dx.doi.org/10.1021/jo00007a019,1991.
APA SU, JY.,ZHONG, YL.,SHI, KL.,QI, C.,SNYDER, JK.,...&胡盛志.(1991).CLAVUDIOL-A AND CLAVIROLIDE-A, 2 MARINE DOLABELLANE DITERPENES FROM THE SOFT CORAL CLAVULARIA-VIRIDIS.http://dx.doi.org/10.1021/jo00007a019.
MLA SU, JY,et al."CLAVUDIOL-A AND CLAVIROLIDE-A, 2 MARINE DOLABELLANE DITERPENES FROM THE SOFT CORAL CLAVULARIA-VIRIDIS".http://dx.doi.org/10.1021/jo00007a019 (1991).
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