| Versatile and chemoselective transformation of aliphatic and aromatic secondary amides to nitriles | |
| Hui Geng ; Pei-Qiang Huang ; Huang PQ(黄培强) | |
| 2015-06-10 | |
| 关键词 | Synthetic methods Secondary amides Nitriles One-pot reaction Chemoselectivity |
| 英文摘要 | 通讯作者地址: Huang, PQ; Triflic anhydride in combination with 2-fluoropyridine effectively dehydrates secondary amides to afford nitriles under mild reaction conditions. The reaction is general in scope and compatible with the use of aliphatic, alpha,beta-unsaturated, aromatic, and heteroaromatic amides bearing either secondary, tertiary, or benzylic N-alkyl groups. The reaction also shows good to excellent chemoselectivity for the secondary amide and tolerates several labile functional groups.; Natural Science Foundation of China (NSFC) 21332007 Program for Changjiang Scholars and Innovative Research Team in University of the Ministry of Education of China |
| 语种 | 英语 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 内容类型 | 期刊论文 |
| 源URL | [http://dspace.xmu.edu.cn/handle/2288/85022]  |
| 专题 | 化学化工－已发表论文 |
| 推荐引用方式 GB/T 7714 | Hui Geng,Pei-Qiang Huang,Huang PQ. Versatile and chemoselective transformation of aliphatic and aromatic secondary amides to nitriles[J],2015. |
| APA | Hui Geng,Pei-Qiang Huang,&黄培强.(2015).Versatile and chemoselective transformation of aliphatic and aromatic secondary amides to nitriles.. |
| MLA | Hui Geng,et al."Versatile and chemoselective transformation of aliphatic and aromatic secondary amides to nitriles".(2015). |
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