Syntheses, structures, thermal stabilities and photoluminescent properties of three silver(I) complexes of 2-ethyl-3-methylpyrazine and different aromatic dicarboxylates with various silver units | |
Ting Zhang ; Hong-Xin Mei ; Dan-Feng Wang ; Rong-Bin Huang ; Huang RB(黄荣彬) ; Lan-Sun Zheng ; Zheng LS(郑兰荪) | |
2015-07-15 | |
关键词 | Silver complexes Pyrazine Aromatic dicarboxylate Structural diversity Various silver units Photoluminescence |
英文摘要 | 通讯作者地址: Huang, RB; Three new silver(I) coordination compounds based on 2-ethyl-3-methylpyrazine (epyz), [Ag-2(epyz)(pta] (1), [Ag-4(epyz)(2)(ipa)(2)] (2) and [Ag-8(epyz)(4)(npa)(4)] (3, H(2)pta = o-phthalic acid, H(2)ipa = m-phthalic acid, H(2)npa = 1,4-napthalenedicarboxylic acid), have been synthesized and have been characterized by elemental analyses, IR spectra and single-crystal X-ray diffraction. Complex 1 shows a two-dimensional network comprising Ag-2 units linked by the organic ligands. In complex 2, tetrahedral Ag4 units are bridged by the organic linkers into a double-layer structure. In complex 3, the chains with alternating Ag-3 and Ag-5 units are connected by the organic ligands into a three-dimensional framework. The structural diversity of these compounds and the Ag units is highly dependent on different carboxylates and the coordination modes of the epyz ligand. The thermal stabilities and photoluminescence behaviors of these complexes were also discussed. |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/85002] |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Ting Zhang,Hong-Xin Mei,Dan-Feng Wang,et al. Syntheses, structures, thermal stabilities and photoluminescent properties of three silver(I) complexes of 2-ethyl-3-methylpyrazine and different aromatic dicarboxylates with various silver units[J],2015. |
APA | Ting Zhang.,Hong-Xin Mei.,Dan-Feng Wang.,Rong-Bin Huang.,黄荣彬.,...&郑兰荪.(2015).Syntheses, structures, thermal stabilities and photoluminescent properties of three silver(I) complexes of 2-ethyl-3-methylpyrazine and different aromatic dicarboxylates with various silver units.. |
MLA | Ting Zhang,et al."Syntheses, structures, thermal stabilities and photoluminescent properties of three silver(I) complexes of 2-ethyl-3-methylpyrazine and different aromatic dicarboxylates with various silver units".(2015). |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论