QQ客服 官方微博 反馈留言

	Capturing the Long-Sought Small-Bandgap Endohedral Fullerene Sc3N@C-82 with Low Kinetic Stability
	Tao Wei ( Univ Sci & Technol China) ; Song Wang ( Univ Sci & Technol China) ; Fupin Liu ( Univ Sci & Technol China) ; Yuanzhi Tan ; Tan YZ(谭元植) ; Xianjun Zhu ( Univ Sci & Technol China) ; Suyuan Xie ; Xie SY(谢素原) ; Shangfeng Yang （ Univ Sci & Technol China）
	2015-05-04
关键词	ISOLATED PENTAGON RULE NITRIDE CLUSTER FULLERENES STRUCTURAL-CHARACTERIZATION METALLOFULLERENE FAMILY MOLECULAR-STRUCTURES CARBIDE CLUSTER I-H-C-80 CAGE D-5H ISOMERS I-H CLUSTERFULLERENES
英文摘要	通讯作者地址: Yang, SF; The long-sought small-bandgap endohedral fullerene Sc3N@C-82 with low kinetic stability has been successfully synthesized and isolated for the first time, for which the molecular structure has been unambiguously determined as Sc3N@C-82-C-2v(39718) by single crystal X-ray diffraction. The C-82-C-2v(39718) (or labeled as C-82-C-2v(9) according to the conventional numbering of the isolated pentagon rule (IPR) isomers based on the Fowler-Monolopoulos spiral algorithm) isomeric cage of Sc3N@C-82 agrees well with its most stable isomer previously predicted by DFT computations and is dramatically different to those of the reported counterparts M3N@C-82-Cs(39663) (M = Gd, Y) based on a non-IPR C-82 isomer, revealing the strong dependence of the cage isomeric structure on the size of the encaged metal for C-82-based metal nitride clusterfullerenes (NCFs).; National Natural Science Foundation of China 21132007 2137116 U1205111 National Basic Research Program of China 2011CB921400 973 project 2014CB845601
语种	英语
出版者	AMER CHEMICAL SOC
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/84897]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Tao Wei ,Song Wang ,Fupin Liu ,et al. Capturing the Long-Sought Small-Bandgap Endohedral Fullerene Sc3N@C-82 with Low Kinetic Stability[J],2015.
APA	Tao Wei .,Song Wang .,Fupin Liu .,Yuanzhi Tan.,谭元植.,...&Shangfeng Yang .(2015).Capturing the Long-Sought Small-Bandgap Endohedral Fullerene Sc3N@C-82 with Low Kinetic Stability..
MLA	Tao Wei ,et al."Capturing the Long-Sought Small-Bandgap Endohedral Fullerene Sc3N@C-82 with Low Kinetic Stability".(2015).

个性服务

查看访问统计

相关权益政策

暂无数据

收藏/分享

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。