Iron-Catalyzed Highly Enantioselective Reduction of Aromatic Ketones with Chiral P2N4-Type Macrocycles

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	Iron-Catalyzed Highly Enantioselective Reduction of Aromatic Ketones with Chiral P2N4-Type Macrocycles
	Yu, Shenluan ; Shen, Weiyi ; Li, Yanyun ; Dong, Zhenrong ; Xu, Yaqing ; Li, Qi ; Zhang, Juanni ; Gao, Jingxing ; Gao JX(高景星)
刊名	http://dx.doi.org/10.1002/adsc.201100733
	2012-03
关键词	ASYMMETRIC TRANSFER HYDROGENATION TETRADENTATE LIGAND RUTHENIUM COMPLEXES CARBONYL-COMPOUNDS IRIDIUM CATALYST PNNP LIGAND HYDROSILYLATION ACETOPHENONE SYSTEMS WATER
英文摘要	National Natural Science Foundation of China [20423002, 20923004, 21173176]; Program for Changjiang Scholars and Innovative Research Team in University [IRT1036]; State Key Laboratory of Physical Chemistry of Solid Surfaces; Novel P2N4-donors containing chiral 22-membered macrocyclic ligands have been synthesized and the structures have been determined by an X-ray diffraction study. The catalytic systems in situ generated from triiron dodecarbonyl, Fe3(CO)12, and the chiral macrocyclic ligand exhibited high activity (TOF up to 1940 h-1) and excellent enantioselectivity with up to 99% ee in the asymmetric transfer hydrogenation of various aromatic ketones.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/64319]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Yu, Shenluan,Shen, Weiyi,Li, Yanyun,et al. Iron-Catalyzed Highly Enantioselective Reduction of Aromatic Ketones with Chiral P2N4-Type Macrocycles[J]. http://dx.doi.org/10.1002/adsc.201100733,2012.
APA	Yu, Shenluan.,Shen, Weiyi.,Li, Yanyun.,Dong, Zhenrong.,Xu, Yaqing.,...&高景星.(2012).Iron-Catalyzed Highly Enantioselective Reduction of Aromatic Ketones with Chiral P2N4-Type Macrocycles.http://dx.doi.org/10.1002/adsc.201100733.
MLA	Yu, Shenluan,et al."Iron-Catalyzed Highly Enantioselective Reduction of Aromatic Ketones with Chiral P2N4-Type Macrocycles".http://dx.doi.org/10.1002/adsc.201100733 (2012).