Diamminesilver(I) bis(2-amino-5-nitrobenzoato-kappa O-2(1),O-1 ')silver(I): a two-dimensional supramolecular sheet with a short intersheet distance containing a rare four-coordinate planar silver(I) centre

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	Diamminesilver(I) bis(2-amino-5-nitrobenzoato-kappa O-2(1),O-1 ')silver(I): a two-dimensional supramolecular sheet with a short intersheet distance containing a rare four-coordinate planar silver(I) centre
	Sun, D. ; Zhang, N. ; Huang, R. B. ; Zheng, L. S. ; Zheng LS(郑兰荪)
刊名	http://dx.doi.org/10.1107/S0108270110020585
	2010-07
关键词	COORDINATION POLYMERS LIGANDS ARCHITECTURES COMPLEX
英文摘要	National Natural Science Foundation of China [20721001]; 973 Project [2007CB815301]; The asymmetric unit of the title compound, [Ag(NH3)(2)]-[Ag(C7H5N2O4)(2)], comprises half an [Ag(NH3)(2)](+) cation and half an [Ag(anbz)(2)](-) anion (anbz is 2-amino-5-nitrobenzoate). Both Ag-I ions are located on inversion centres. The cation has a linear coordination geometry with two symmetry-related ammine ligands. The Ag-I cation in the anionic part shows a rare four-coordinate planar geometry completed by two chelating symmetry-related anbz ligands. Intra- and intermolecular N-H center dot center dot center dot O hydrogen bonds create a slightly undulating two-dimensional supramolecular sheet. Adjacent sheets are only ca 3.3 angstrom apart. Ag center dot center dot center dot O, Ag center dot center dot center dot N and pi-pi stacking interactions consolidate the packing of the molecules in the solid state.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/63821]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Sun, D.,Zhang, N.,Huang, R. B.,et al. Diamminesilver(I) bis(2-amino-5-nitrobenzoato-kappa O-2(1),O-1 ')silver(I): a two-dimensional supramolecular sheet with a short intersheet distance containing a rare four-coordinate planar silver(I) centre[J]. http://dx.doi.org/10.1107/S0108270110020585,2010.
APA	Sun, D.,Zhang, N.,Huang, R. B.,Zheng, L. S.,&郑兰荪.(2010).Diamminesilver(I) bis(2-amino-5-nitrobenzoato-kappa O-2(1),O-1 ')silver(I): a two-dimensional supramolecular sheet with a short intersheet distance containing a rare four-coordinate planar silver(I) centre.http://dx.doi.org/10.1107/S0108270110020585.
MLA	Sun, D.,et al."Diamminesilver(I) bis(2-amino-5-nitrobenzoato-kappa O-2(1),O-1 ')silver(I): a two-dimensional supramolecular sheet with a short intersheet distance containing a rare four-coordinate planar silver(I) centre".http://dx.doi.org/10.1107/S0108270110020585 (2010).