Synthesis and characterization of a high selective mercury(II)-imprinted polymer using novel aminothiol monomer | |
Firouzzare, Mahmoud ; Wang, Qiuquan ; Wang QQ(王秋泉) | |
刊名 | http://dx.doi.org/10.1016/j.talanta.2012.09.023 |
2012-11-15 | |
关键词 | SOLID-PHASE EXTRACTION MOLECULARLY IMPRINTED POLYMERS METAL-IONS POLY(4-VINYLPYRIDINE) RESINS PRECONCENTRATIVE SEPARATION RECOGNITION ADSORPTION MICROBEADS PARTICLES MERCURY |
英文摘要 | Natural Science Foundation of China [20775062, 20535020]; A novel aminothiol monomer was synthesized from' 2-mercaptoethylamine for complexing the Hg(II) ion. The synthesized complex monomer has been used for preparing the Hg(II)-imprinted polymer by radical copolymerization with methacrylic acid and ethylene glycol dimethacrylate and AIBN as the functional monomer, cross-linker and initiator respectively in the presence of a binary porogen of DMSO and toluene. The results of batch procedures showed that the Hg(II)-imprinted polymer has adsorption capacity of 28 mg g(-1). The distribution ratio (K-d) values of the Hg(II)-imprinted polymer increases for mercury with respect to both K-d values of CH3Hg(I), Zn(II), Cd(II) and non-imprinted polymers. The relative selective factors k for Hg(II)/ CH3Hg(I), Hg(II)/Cd(II) and Hg(II)/Zn(II) are 15.5, 12.5, and 20.6, which are greater than 1. The thermal stability has also been investigated by thermogravimetric analysis which shows that the polymerization process increases the thermal stability up to 125 degrees C. (C) 2012 Elsevier B.V. All rights reserved. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/62777] |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Firouzzare, Mahmoud,Wang, Qiuquan,Wang QQ. Synthesis and characterization of a high selective mercury(II)-imprinted polymer using novel aminothiol monomer[J]. http://dx.doi.org/10.1016/j.talanta.2012.09.023,2012. |
APA | Firouzzare, Mahmoud,Wang, Qiuquan,&王秋泉.(2012).Synthesis and characterization of a high selective mercury(II)-imprinted polymer using novel aminothiol monomer.http://dx.doi.org/10.1016/j.talanta.2012.09.023. |
MLA | Firouzzare, Mahmoud,et al."Synthesis and characterization of a high selective mercury(II)-imprinted polymer using novel aminothiol monomer".http://dx.doi.org/10.1016/j.talanta.2012.09.023 (2012). |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论