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	Chiral phosphine ligands derived from sugars 6 Syntheses and spectroscopic studies on rhodium complexes with a new type of chiral phosphines
	Shi, J. C. ; Wu, D. X. ; Wen, T. B. ; Wen TB(温庭斌) ; Lu, G. T. ; Liu, Q. T. ; Kang, B. S.
	1996
关键词	CATALYZED HYDROFORMYLATION REACTIONS SOLID-STATE STEREOCHEMISTRY DIPHOSPHINES PHELLANPHOS PHOSPHOLES NOPAPHOS SYSTEMS
英文摘要	Methyl 4,6-O-benzylidene-3-deoxy-3-(diphenylphosphino)-alpha-D-altropyranoside (1) and methyl 4,6-O-benzylidene-2-deoxy-2-(diphenylphosphino)-alpha-D-altropyranoside (2) were prepared from methyl 2,3-anhydro-4,6-O-benzylidene-alpha-D-mannopyranoside and methyl 2,3-anhydro-4,6-O-benzylidene-alpha-D-allopyranoside, respectively, via regioselective and stereospecific ring-opening reactions in high yields. Ligands 1 and 2 reacted with [{Rh(CO)(2)Cl}(2)] to give trans-[(P')(2)Rh(CO)Cl] (3, P' = 1; 4, P' = 2). Compounds 1-4 have been characterized by elemental analyses, multinuclear NMR, IR and Raman, mass spectroscopic investigations. Copyright (C) 1996 Elsevier Science Ltd
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/62732]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Shi, J. C.,Wu, D. X.,Wen, T. B.,et al. Chiral phosphine ligands derived from sugars 6 Syntheses and spectroscopic studies on rhodium complexes with a new type of chiral phosphines[J],1996.
APA	Shi, J. C..,Wu, D. X..,Wen, T. B..,温庭斌.,Lu, G. T..,...&Kang, B. S..(1996).Chiral phosphine ligands derived from sugars 6 Syntheses and spectroscopic studies on rhodium complexes with a new type of chiral phosphines..
MLA	Shi, J. C.,et al."Chiral phosphine ligands derived from sugars 6 Syntheses and spectroscopic studies on rhodium complexes with a new type of chiral phosphines".(1996).

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