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	Syntheses and crystal structures of copper(I) complexes with alkyl-thioallophanate derivatives
	Shen, X. ; Wen, T. B. ; Liu, Q. T. ; Huang, X. Y. ; Kang, B. S. ; Wu, X. L. ; Huang, Z. S. ; Gu, L. Q. ; Wen TB(温庭斌)
	1997
关键词	Cu-I complexes thioureas syntheses X-ray structures H-1 NMR C-13 NMR
英文摘要	The reaction of CuCl2 . 2H(2)O with N-(p-nitrophenyl)-N'-butoxycarbonyl)-thiourea (H(2)nbt) and N-(o-nitrophenyl)-N'-(ethoxycarbonyl)-thiourea (H(2)net) gave two copper(I) complexes, [Cu(H(2)nbt)(2)Cl](2), 1, and Cu(H(2)net)(2)Cl, 2, respectively. In complex 1, the ligand H(2)nbt is S,S-bonded to two Cu atoms, and the two ligand molecules exchange ''long'' Cu--S interactions (Cu--S = 2.700 Angstrom) forming a dimer, in which the Cu atom has a distorted tetrahedral coordination [Cl--Cu--S(1) = 119.9(1), Cl--Cu--S(2) = 122.9(1) and S(1)--Cu--S(2) = 108.4(1)degrees] and is 0.387(2) Angstrom, from th basal S, S, Cl with unequal Cu--S [2.253(3), 2.244(3) Angstrom] and Cu--Cl [2.247(3) Angstrom] bonds. In complex 2, the copper (I) atom is in a trigonal planar geometry [Cl--Cu--S(1) = 120.53(5), Cl--Cu--S(2) = 118.43(5) and S(1)--Cu--S(2) = 119.16(5)degrees] with two unequal Cu--S [2.228(1), 2.232(1) Angstrom] and Cu--Cl [2.251(1) Angstrom] bonds. (C) 1997 Elsvier Science Ltd.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/62729]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Shen, X.,Wen, T. B.,Liu, Q. T.,et al. Syntheses and crystal structures of copper(I) complexes with alkyl-thioallophanate derivatives[J],1997.
APA	Shen, X..,Wen, T. B..,Liu, Q. T..,Huang, X. Y..,Kang, B. S..,...&温庭斌.(1997).Syntheses and crystal structures of copper(I) complexes with alkyl-thioallophanate derivatives..
MLA	Shen, X.,et al."Syntheses and crystal structures of copper(I) complexes with alkyl-thioallophanate derivatives".(1997).

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