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	The selective preparation of an aluminum oxide and its isomeric C-H-activated hydroxide
	Zhu, H. P. ; Chai, J. F. ; Jancik, V. ; Roesky, H. W. ; Merrill, W. A. ; Power, P. P. ; Zhu HP(朱红平)
	2005
关键词	BETA-DIKETIMINATE LIGAND AL-O STRUCTURAL-CHARACTERIZATION TERT-BUTYLALUMINUM POLYMERIZATION HYDROLYSIS REACTIVITY COMPLEXES CATALYSTS DIOXYGEN
英文摘要	An aluminum oxide [LAlO]2 (1) has been prepared by the oxidative addition of aluminum(I) monomer LAl (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) with molecular oxygen. The short Al-O bonds in Al2(mu-O)2 result in short Al...Al contacts and subsequent steric crowding of the Ar substituents from the two oriented L. 1 hydrolyzes to form [LAl(OH)]2(mu-O) (2). A C-H-activated aluminum hydroxide 4, an isomer of 1, however, is obtained by hydrolysis of the bulky aluminum amide 3 rather than by a conversion by high temperature treatment of 1. This indicates selective preparation of isomers 1 and 4.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/62151]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Zhu, H. P.,Chai, J. F.,Jancik, V.,et al. The selective preparation of an aluminum oxide and its isomeric C-H-activated hydroxide[J],2005.
APA	Zhu, H. P..,Chai, J. F..,Jancik, V..,Roesky, H. W..,Merrill, W. A..,...&朱红平.(2005).The selective preparation of an aluminum oxide and its isomeric C-H-activated hydroxide..
MLA	Zhu, H. P.,et al."The selective preparation of an aluminum oxide and its isomeric C-H-activated hydroxide".(2005).

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