Solvent Control over Structural Diversity of Two Manganese Complexes Based on Furan-2,5-dicaboxylate | |
Chen Wen-Xian ; Wu Geng-Huang ; Zhuang Gui-Lin ; Kong Xiang-Jian ; Kong XJ(孔祥建) ; Long La-Sheng ; Long LS(龙腊生) ; Huang Rong-Bin ; Huang RB(黄荣彬) ; Zheng Lan-Sun ; Zheng LS(郑兰荪) | |
2011 | |
关键词 | Solvent effect Metal-organic framework Magnetism |
英文摘要 | Two complexes, namely, Mn(FDC)(H(2)O)(3) (1) and [H(2)N(CH(3))(2)](2)center dot[Mn(3)(FDC)(4)]center dot 2DMF center dot H(2)O (2) (H2 FDC = Furan-2,5-dicarboxylic acid), were synthesized via the solvothermal reaction of manganese(H) chloride and furan-2,5-dicarboxylate acid under different solvent conditions. Single-crystal analysis reveals that one-dimensional complex 1 was obtained when the reaction was carried out in DMF/H(2)O, while three-dimensional complex 2 was synthesized when the reaction was carried out in DMF. Variable-temperature magnetic measurements and Quantum Monte Carlo(QMC) simulation indicate that both the complexes exhibit antiferromagnetic characteristic. |
语种 | 英语 |
出版者 | HIGHER EDUCATION PRESS |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/11746] |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Chen Wen-Xian,Wu Geng-Huang,Zhuang Gui-Lin,et al. Solvent Control over Structural Diversity of Two Manganese Complexes Based on Furan-2,5-dicaboxylate[J],2011. |
APA | Chen Wen-Xian.,Wu Geng-Huang.,Zhuang Gui-Lin.,Kong Xiang-Jian.,孔祥建.,...&郑兰荪.(2011).Solvent Control over Structural Diversity of Two Manganese Complexes Based on Furan-2,5-dicaboxylate.. |
MLA | Chen Wen-Xian,et al."Solvent Control over Structural Diversity of Two Manganese Complexes Based on Furan-2,5-dicaboxylate".(2011). |
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