A concise and fully selective synthesis of the ant venom alkaloid (3S,5R,8S,9S)-3-butyl-5-propyl-8-hydroxyindolizidine | |
Lin, Geng-Jie ; Huang, Pei-Qiang ; Huang PQ(黄培强) | |
2009 | |
英文摘要 | A seven-step synthesis of (3S,5R,8S,9S)-3-butyl-5-propyl-8-hydroxyindolizidine (2), an ant venom alkaloid isolated from Myrmicaria melanogaster, is disclosed with an overall yield of 28.9%. The key feature of the synthesis is the use of the iodocyclization for the introduction of the hydroxyl group of the 3-piperidinol. Remarkably, all the reaction steps proceeded with excellent chemo-, regio- and/or diastereoselectivities.; NSF of China [20832005]; National Basic Research Program (973 Program) of China [2010CB833206] |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
内容类型 | 期刊论文 |
源URL | [http://dx.doi.org/doi:10.1039/B912190K] ![]() |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Lin, Geng-Jie,Huang, Pei-Qiang,Huang PQ. A concise and fully selective synthesis of the ant venom alkaloid (3S,5R,8S,9S)-3-butyl-5-propyl-8-hydroxyindolizidine[J],2009. |
APA | Lin, Geng-Jie,Huang, Pei-Qiang,&黄培强.(2009).A concise and fully selective synthesis of the ant venom alkaloid (3S,5R,8S,9S)-3-butyl-5-propyl-8-hydroxyindolizidine.. |
MLA | Lin, Geng-Jie,et al."A concise and fully selective synthesis of the ant venom alkaloid (3S,5R,8S,9S)-3-butyl-5-propyl-8-hydroxyindolizidine".(2009). |
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