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	The stabilization of fused-pentagon fullerene molecules
	Yuan-Zhi Tan ; Tan YZ(谭元植) ; Su-Yuan Xie ; Xie SY(谢素原) ; Rong-Bin Huang ; Huang RB(黄荣彬) ; Lan-Sun Zheng ; Zheng LS(郑兰荪)
	2009-09
关键词	DENSITY-FUNCTIONAL THEORY METAL-CARBIDE ENDOFULLERENE IPR CARBON CAGE ENDOHEDRAL METALLOFULLERENES ELECTRONIC-PROPERTIES STABLE DERIVATIVES CHEMICAL OXIDATION MATERIALS SCIENCE 4-MEMBERED RING NITRIDE CLUSTER
英文摘要	The isolated pentagon rule (IPR) is now widely accepted as a general rule for determining the stability of all-carbon fullerene cages composed of hexagons and pentagons. Fullerenes that violate this rule have been deemed too reactive to be synthesized. The stabilization of non-IPR endohedral fullerenes depends on charge transfer from the encapsulated metal clusters (endoclusters) to fullerene cages, the electronic properties of empty all-carbon cages, the matching size and geometries of fullerene and endocluster, as well as the strong coordination of the metal ions to fused pentagons. The stability of non-IPR exohedral fullerenes can be rationalized primarily by both the 'strain-relief' and 'local-aromaticity' principles. This Review focuses on recent work on stabilization of non-IPR fullerenes, including theoretical and empirical principles, experimental methods, and molecular structures of fused-pentagon fullerenes characterized so far. The special chemical properties of non-IPR fullerenes that distinguish them from IPR-satisfying ones are also emphasized.; NNSFC 20525103,20531050,20721001 973 Program 2007CB815301
语种	英语
出版者	NATURE PUBLISHING GROUP
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/3208]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Yuan-Zhi Tan,Tan YZ,Su-Yuan Xie,et al. The stabilization of fused-pentagon fullerene molecules[J],2009.
APA	Yuan-Zhi Tan.,谭元植.,Su-Yuan Xie.,谢素原.,Rong-Bin Huang.,...&郑兰荪.(2009).The stabilization of fused-pentagon fullerene molecules..
MLA	Yuan-Zhi Tan,et al."The stabilization of fused-pentagon fullerene molecules".(2009).

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