取代四苯基钴卟啉催化剂的合成及构效关系研究 | |
张天慧 ; 佘远斌 ; 王兰芝 | |
2012-04-24 ; 2012-04-24 | |
关键词 | 钴卟啉 合成 构效关系 |
中文摘要 | The catalytic activities of cobalt porphyrin catalysts vary with their structures. Consequently exploring the QSAR of cobalt porphyrin catalysts was one of the extremely attractive investigations. In this paper, substituted cobalt-porphyrin catalysts were synthesized and characterized. Catalytic activities of these catalysts were investigated by means of dioxygen liquid-phase oxidation of p-nitrotoluene (PNT) to p-nitrobenaldehyde as the model reaction. The QSAR of cobalt porphyrin catalysts was emphatically investigated and the regression equation TON=39639.79-440.24ELUMO-3054.11EL-H was obtained. |
会议网址 | http://guest.cnki.net/grid2008/brief/detailj.aspx?filename=ZGHY200607001067&dbname=CPFD2006 |
会议录出版者 | 中国吉林长春 |
内容类型 | 会议论文 |
源URL | [http://hdl.handle.net/123456789/18435] |
专题 | 北京工业大学 |
推荐引用方式 GB/T 7714 | 张天慧,佘远斌,王兰芝. 取代四苯基钴卟啉催化剂的合成及构效关系研究[C]. 见:.http://guest.cnki.net/grid2008/brief/detailj.aspx?filename=ZGHY200607001067&dbname=CPFD2006. |
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