CORC  > 北京工业大学
取代四苯基钴卟啉催化剂的合成及构效关系研究
张天慧 ; 佘远斌 ; 王兰芝
2012-04-24 ; 2012-04-24
关键词钴卟啉 合成 构效关系
中文摘要The catalytic activities of cobalt porphyrin catalysts vary with their structures. Consequently exploring the QSAR of cobalt porphyrin catalysts was one of the extremely attractive investigations. In this paper, substituted cobalt-porphyrin catalysts were synthesized and characterized. Catalytic activities of these catalysts were investigated by means of dioxygen liquid-phase oxidation of p-nitrotoluene (PNT) to p-nitrobenaldehyde as the model reaction. The QSAR of cobalt porphyrin catalysts was emphatically investigated and the regression equation TON=39639.79-440.24ELUMO-3054.11EL-H was obtained.
会议网址http://guest.cnki.net/grid2008/brief/detailj.aspx?filename=ZGHY200607001067&dbname=CPFD2006
会议录出版者中国吉林长春
内容类型会议论文
源URL[http://hdl.handle.net/123456789/18435]  
专题北京工业大学
推荐引用方式
GB/T 7714
张天慧,佘远斌,王兰芝. 取代四苯基钴卟啉催化剂的合成及构效关系研究[C]. 见:.http://guest.cnki.net/grid2008/brief/detailj.aspx?filename=ZGHY200607001067&dbname=CPFD2006.
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