Dynamical similarity in the highly excited vibrations of HCP and DCP: The dynamical potential approach | |
Fang, Chao ; Wu, Guozhen | |
2010-10-12 ; 2010-10-12 | |
关键词 | Dynamical similarity HCP DCP Highly excited vibration Dynamical potential EMISSION PUMPING SPECTROSCOPY BREAKING INTERNAL-ROTATION ISOMERIZATION STATES BOND PHOSPHAETHYNE ASSIGNMENT SIGNATURES SPECTRA POLYAD Chemistry, Physical |
中文摘要 | The fixed points in the dynamical potentials of phosphaethyne (HCP) and deuterated phosphaethyne (DCP) derived in the coset space are identified and shown to govern the various quantal environments in which the vibrational states lie. The state dynamics is interpreted and classified by the classical actions and action integrals. This is closely related to the fixed point structure. Localized modes even at high excitation are identified. Most important is that the dynamical similarity between these two systems is identified which enables us to understand the DCP dynamics simply from that of HCP without repeated elaboration. (C) 2009 Elsevier B.V. All rights reserved. |
语种 | 英语 ; 英语 |
出版者 | ELSEVIER SCIENCE BV ; AMSTERDAM ; PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/81528] |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Fang, Chao,Wu, Guozhen. Dynamical similarity in the highly excited vibrations of HCP and DCP: The dynamical potential approach[J],2010, 2010. |
APA | Fang, Chao,&Wu, Guozhen.(2010).Dynamical similarity in the highly excited vibrations of HCP and DCP: The dynamical potential approach.. |
MLA | Fang, Chao,et al."Dynamical similarity in the highly excited vibrations of HCP and DCP: The dynamical potential approach".(2010). |
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