Vertically aligned carbon nanotube arrays grown on a lamellar catalyst by fluidized bed catalytic chemical vapor deposition | |
Zhang, Qiang ; Zhao, Meng-Qiang ; Huang, Jia-Qi ; Liu, Yi ; Wang, Yao ; Qian, Wei-Zhong ; Wei, Fei | |
2010-10-12 ; 2010-10-12 | |
关键词 | LARGE-SCALE PRODUCTION AGGLOMERATE STRUCTURE MASS-PRODUCTION HIGH-QUALITY REACTOR GAS CVD DECOMPOSITION METHANE SPHERES Chemistry, Physical Materials Science, Multidisciplinary |
中文摘要 | Large amount of vertically aligned carbon nanotube (CNT) arrays were grown among the layers of vermiculite in a fluidized bed reactor. The vermiculite, which was 100-300 mu m in diameter and merely 50-100 mu m thick, served as catalyst carrier. The Fe/Mo active phase was randomly distributed among the layers of vermiculite. The catalyst shows good fluidization characteristics, and can easily be fluidized in the reactor within a large range of gas velocities. When ethylene is used as carbon source, CNT arrays with a relatively uniform length and CNT diameter can be synthesized. The CNTs in the arrays are with an inner diameter of 3-6 nm, an outer diameter of 7-12 nm, and a length of up to several tens of micrometers. The as-grown CNTs possess good alignment and exhibit a purity of ca. 84%. Unlike CNT arrays grown on a plane or spherical substrate, the CNT arrays grown in the fluidized bed remain their particle morphologies with a size of 50-300 mu m. and the good fluidization characteristics were preserved accordingly. (C) 2009 Elsevier Ltd. All rights reserved. |
语种 | 英语 ; 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD ; OXFORD ; THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/79445] |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Zhang, Qiang,Zhao, Meng-Qiang,Huang, Jia-Qi,et al. Vertically aligned carbon nanotube arrays grown on a lamellar catalyst by fluidized bed catalytic chemical vapor deposition[J],2010, 2010. |
APA | Zhang, Qiang.,Zhao, Meng-Qiang.,Huang, Jia-Qi.,Liu, Yi.,Wang, Yao.,...&Wei, Fei.(2010).Vertically aligned carbon nanotube arrays grown on a lamellar catalyst by fluidized bed catalytic chemical vapor deposition.. |
MLA | Zhang, Qiang,et al."Vertically aligned carbon nanotube arrays grown on a lamellar catalyst by fluidized bed catalytic chemical vapor deposition".(2010). |
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