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Vertically aligned carbon nanotube arrays grown on a lamellar catalyst by fluidized bed catalytic chemical vapor deposition
Zhang, Qiang ; Zhao, Meng-Qiang ; Huang, Jia-Qi ; Liu, Yi ; Wang, Yao ; Qian, Wei-Zhong ; Wei, Fei
2010-10-12 ; 2010-10-12
关键词LARGE-SCALE PRODUCTION AGGLOMERATE STRUCTURE MASS-PRODUCTION HIGH-QUALITY REACTOR GAS CVD DECOMPOSITION METHANE SPHERES Chemistry, Physical Materials Science, Multidisciplinary
中文摘要Large amount of vertically aligned carbon nanotube (CNT) arrays were grown among the layers of vermiculite in a fluidized bed reactor. The vermiculite, which was 100-300 mu m in diameter and merely 50-100 mu m thick, served as catalyst carrier. The Fe/Mo active phase was randomly distributed among the layers of vermiculite. The catalyst shows good fluidization characteristics, and can easily be fluidized in the reactor within a large range of gas velocities. When ethylene is used as carbon source, CNT arrays with a relatively uniform length and CNT diameter can be synthesized. The CNTs in the arrays are with an inner diameter of 3-6 nm, an outer diameter of 7-12 nm, and a length of up to several tens of micrometers. The as-grown CNTs possess good alignment and exhibit a purity of ca. 84%. Unlike CNT arrays grown on a plane or spherical substrate, the CNT arrays grown in the fluidized bed remain their particle morphologies with a size of 50-300 mu m. and the good fluidization characteristics were preserved accordingly. (C) 2009 Elsevier Ltd. All rights reserved.
语种英语 ; 英语
出版者PERGAMON-ELSEVIER SCIENCE LTD ; OXFORD ; THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/79445]  
专题清华大学
推荐引用方式
GB/T 7714
Zhang, Qiang,Zhao, Meng-Qiang,Huang, Jia-Qi,et al. Vertically aligned carbon nanotube arrays grown on a lamellar catalyst by fluidized bed catalytic chemical vapor deposition[J],2010, 2010.
APA Zhang, Qiang.,Zhao, Meng-Qiang.,Huang, Jia-Qi.,Liu, Yi.,Wang, Yao.,...&Wei, Fei.(2010).Vertically aligned carbon nanotube arrays grown on a lamellar catalyst by fluidized bed catalytic chemical vapor deposition..
MLA Zhang, Qiang,et al."Vertically aligned carbon nanotube arrays grown on a lamellar catalyst by fluidized bed catalytic chemical vapor deposition".(2010).
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