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Influences of phosphorus pentoxide on sintering behaviors of glass-ceramics from phosphorus slag
Cao Jianwei ; Liang Kaiming ; Li Yaohui
2010-10-12 ; 2010-10-12
关键词Experimental/ glass ceramics particle size phosphorus compounds sintering slag X-ray diffraction/ phosphorus pentoxide sintering glass-ceramics phosphorus slag raw material orthogonal test X-ray diffraction particle size crystalline phase temperature 1000 C to 1050 C P/sub 2/O/sub 5// A8120Q Preparation of glass-based composites A8120E Powder techniques, compaction and sintering/ temperature 1.27315E+03 to 1.32315E+03 K/ P2O5/bin O5/bin P2/bin O/bin P/bin
中文摘要Glass-ceramics were prepared from phosphorus slag as the main raw material by sintering method. The factors influencing the sintering behavior were investigated by orthogonal test and X-ray diffraction. The results show that the dominant factor is sintering temperature, the second is P/sub 2/O/sub 5/ content, the third is the particle size, and the last is the holding time. P/sub 2/O/sub 5/ had a significant effect on the sintering behavior when the other three influential factors were invariable. When the P/sub 2/O/sub 5/ content (mass fraction, the same below) was less than 1.8%, beta -CaSiO/sub 3/ was the main crystalline phase at below 1 000 degrees C and the surface of the glass-ceramics was not smooth. When the P/sub 2/O/sub 5/ content was more than 3.6%, the required sintering temperature was increased to 1 100 degrees C; meanwhile, the required holding time was dramatically prolonged. In this case, Na/sub 2/Ca/sub 2/Si/sub 3/O/sub 9/ became mainly crystalline and the surface of the glass-ceramics was not smooth. As a result, the preferential P/sub 2/O/sub 5/ content was in the range of 1.8%-3.6%, sintering temperature was 1 000-1 050 degrees C, sintering time was 60 min, and glass-ceramics with a smooth and flat surface could be obtained.
语种中文
出版者Chinese Ceramic Society ; China
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/78234]  
专题清华大学
推荐引用方式
GB/T 7714
Cao Jianwei,Liang Kaiming,Li Yaohui. Influences of phosphorus pentoxide on sintering behaviors of glass-ceramics from phosphorus slag[J],2010, 2010.
APA Cao Jianwei,Liang Kaiming,&Li Yaohui.(2010).Influences of phosphorus pentoxide on sintering behaviors of glass-ceramics from phosphorus slag..
MLA Cao Jianwei,et al."Influences of phosphorus pentoxide on sintering behaviors of glass-ceramics from phosphorus slag".(2010).
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