Influences of Co doping on the structural, optical and magnetic properties of ZnO nanorods synthesized by hydrothermal route | |
Wang, Baiqi ; Xia, Chunhui ; Iqbal, Javed ; Tang, Naijun ; Sun, Zengrong ; Lv, Yan ; Wu, Lina | |
2010-10-12 ; 2010-10-12 | |
关键词 | ZnO nanorods Co doping Photoluminescence Ferromagnetism Solution method ROOM-TEMPERATURE FERROMAGNETISM THIN-FILMS NANOWIRES GROWTH ARRAYS PHOTOLUMINESCENCE FABRICATION NANOBELTS Chemistry, Inorganic & Nuclear Chemistry, Physical Physics, Condensed Matter |
中文摘要 | Pure and Co-doped ZnO nanorods have been synthesized by a hydrothermal process. The structure, morphology and properties of as-prepared samples have been studied using X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), photoluminescence (PL) spectrometer as well as by superconducting quantum interference device (SQUID). The structure and morphology analyses show that Co doping can slightly impede the ZnO crystallinity, influence the nanorods morphology. but cannot change the preferred growth orientation of ZnO nanorods. The amount of Co doping contents is about 3.0 at% in ZnO nanorods and dopant Co2+ ions substitute Zn2+ ions sites in ZnO nanocrystal without forming any secondary phase. The optical measurements show that the Co doping can effectively tune energy band structure and enrich surface states in both UV and VL regions, which lead to novel PL properties of ZnO nanorods. in addition, ferromagnetic ordering of the as-synthesized Zn1-xCoxO nanorod arrays has been observed at room temperature, which should be ascribed to sp-d and d-d carrier exchange interactions and presence of abundant defects and oxygen vacancies. (C) 2009 Elsevier Masson SAS. All rights reserved. |
语种 | 英语 ; 英语 |
出版者 | ELSEVIER SCIENCE BV ; AMSTERDAM ; PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/78150] |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Wang, Baiqi,Xia, Chunhui,Iqbal, Javed,et al. Influences of Co doping on the structural, optical and magnetic properties of ZnO nanorods synthesized by hydrothermal route[J],2010, 2010. |
APA | Wang, Baiqi.,Xia, Chunhui.,Iqbal, Javed.,Tang, Naijun.,Sun, Zengrong.,...&Wu, Lina.(2010).Influences of Co doping on the structural, optical and magnetic properties of ZnO nanorods synthesized by hydrothermal route.. |
MLA | Wang, Baiqi,et al."Influences of Co doping on the structural, optical and magnetic properties of ZnO nanorods synthesized by hydrothermal route".(2010). |
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