锆离子轰击对纯锆腐蚀行为的影响 | |
彭德全 ; 白新德 ; 陈宝山 ; PENG Dequan ; BAI Xinde ; Chen Baoshan | |
2010-06-10 ; 2010-06-10 | |
关键词 | 纯锆 耐蚀性 自离子轰击 动电位极化 相转变 Zr, corrosion resistance, self-ion implantation, potentiodynamic polarization, phase transformation TG172 |
其他题名 | INFLUENCE OF Zr-ION IMPLANTATION ON THE CORROSION BEHAVIOR OF ZIRCONIUM |
中文摘要 | 为了研究自离子轰击对纯锆耐蚀性的影响,用MEVVA源对纯锫样品进行了1×1015至2×1017ions/cm2的自离子轰击,注入温度为170℃,加速电压为50 kV.用X射线光电子谱(XPS)对注入表面各元素进行价态分析;用Auger电子能谱(AES)分析氧化膜厚度.三次极化测量用来评价轰击样品在1 mol/L H2SO4溶液中的耐蚀性.用掠射X射线衍射(GAXRD)分析自离子轰击造成的氧化膜相转变.研究表明: 5×1016 Zr ions/cm2自离子轰击样品的耐蚀性最好.对自离子轰击纯锆的腐蚀行为机理进行了讨论.; In order to investigate the affect of self-ion bombardment on the aqueous corrosion behavior of zirconium, the specimens were implanted by zirconium ions with a fluence range from 1×1015 to 2×1017 ions/cm2 at about 170 ℃, using a MEVVA source at an extractation voltage of 50 kV. The valence of the surface layer was analyzed by X-ray photoemission spectroscopy (XPS); the thickness of the oxide film was measured by Auger electron spectroscopy (AES). Three-sweep poten-tiodynamic polarization measurement was used to value the aqueous corrosion resistance of implanted zirconium in 1 mol/L H2SO4 solution. Glancing angle X-ray diffraction (GAXRD) was employed to determine the phase transformation due to the self-ion implantation in the oxide films. It was found that the aqueous corrosion resistance of zirconium implanted with 5×1016 Zr ions/cm2 is the best in all the samples. Finally, the mechanism of the corrosion behavior of the self-ion implanted zirconium is discussed.; 国家重点基础研究发展规划资助项目G2000067207-1 |
语种 | 中文 ; 中文 |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/61317] |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | 彭德全,白新德,陈宝山,等. 锆离子轰击对纯锆腐蚀行为的影响[J],2010, 2010. |
APA | 彭德全,白新德,陈宝山,PENG Dequan,BAI Xinde,&Chen Baoshan.(2010).锆离子轰击对纯锆腐蚀行为的影响.. |
MLA | 彭德全,et al."锆离子轰击对纯锆腐蚀行为的影响".(2010). |
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