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Comparison of corrosion behavior of zirconium bombarded with self-ion and molybdenum ion
Peng, D.Q. ; Bai, X.D. ; Chen, X.W. ; Zhou, Q.G. ; Liu, X.Y. ; Yu, R.H. ; Deng, P.Y.
2010-05-10 ; 2010-05-10
关键词Experimental/ Auger electron spectra corrosion resistance impurity states ion implantation ion-surface impact molybdenum X-ray photoelectron spectra zirconium/ molybdenum ion bombardment self-ion bombardment ions surface density metal vapor vacuum arc source valence states X-ray photoelectron spectroscopy Auger electron spectroscopy polarization curves corrosion resistance molybdenum ion implantation aqueous corrosion XPS AES zirconium implantation corrosion potential 160 degC 40 kV 170 degC 50 kV Zr:Zr Zr:Mo/ A8160B Surface treatment and degradation of metals and alloys A7920N Atom-, molecule-, and ion-surface impact and interactions A6170T Doping and implantation of impurities A7920F Electron-surface impact: Auger emission A7155D Impurity and defect levels in metals, semimetals, and alloys A7320H Surface impurity and defect levels energy levels of adsorbed species A7960C Photoelectron spectra of clean metals/ temperature 4.33E+02 K voltage 4.0E+04 V temperature 4.43E+02 K voltage 5.0E+04 V/ Zr:Zr/sur Zr/sur Zr:Zr/el Zr/el Zr/dop Zr:Mo/sur Mo/sur Zr/sur Zr:Mo/bin Mo/bin Zr/bin Mo/el Zr/el Mo/dop
中文摘要In order to study the effects of zirconium and molybdenum ion bombardment on the aqueous corrosion behavior of zirconium, one group of specimens was implanted with zirconium ions with ions surface densities ranging from 1*10/sup 15/ to 2*10/sup 17/ ions/cm /sup 2/ at about 170 degrees C, using a metal vapor vacuum arc (MEVVA) source operated at an extraction voltage of 50 kV. The other group of specimens was bombarded with molybdenum ion with ions surface densities ranging from 1*10/sup 16/ to 5*10/sup 17/ ions/cm /sup 2/ at about 160 degrees C, using a MEVVA source operated at an extraction voltage of 40 kV. The valence states and depth distribution of elements in the surface of the samples were analyzed by X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES), respectively. Polarization curves measurement was employed to evaluate the aqueous corrosion resistance of the zirconium samples in a 1N H/sub 2/SO/sub 4/ solution. It was found that the aqueous corrosion resistance of zirconium implanted with 5*10/sup 16/ Zr ions/cm/sup 2/ is the best in first group samples. For molybdenum ion implantation, the aqueous corrosion resistance of samples declined with raising ions surface densities. The natural corrosion potentials of zirconium samples bombarded with self-ions were more negative than that of the as-received zirconium. While, as for molybdenum ion implantation, the results are opposite. Finally, the mechanisms of the corrosion behavior of the zirconium samples implanted with zirconium and molybdenum ions are discussed.
语种英语 ; 英语
出版者Elsevier ; USA
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/20843]  
专题清华大学
推荐引用方式
GB/T 7714
Peng, D.Q.,Bai, X.D.,Chen, X.W.,et al. Comparison of corrosion behavior of zirconium bombarded with self-ion and molybdenum ion[J],2010, 2010.
APA Peng, D.Q..,Bai, X.D..,Chen, X.W..,Zhou, Q.G..,Liu, X.Y..,...&Deng, P.Y..(2010).Comparison of corrosion behavior of zirconium bombarded with self-ion and molybdenum ion..
MLA Peng, D.Q.,et al."Comparison of corrosion behavior of zirconium bombarded with self-ion and molybdenum ion".(2010).
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