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	Two new bromo-functionalized organoimido derivatives of hexamolybdate: Synthesis, crystal structure, spectroscopic and electrochemical studies
	Li, Qiang ; Zhu, Li ; Meng, Xianggao ; Zhu, Yulin ; Hao, Jian ; Wei, Yongge
	2010-05-06 ; 2010-05-06
关键词	organic derivatives polyoxometalates DCC aromatic amine halides organic-inorganic hybrids crystal structures AROMATIC-AMINES POLYOXOMETALATE COMPLEXES CLUSTERS LIGANDS 2 OXO Chemistry, Inorganic & Nuclear
中文摘要	Two organic-inorganic hybrid compounds, (Bu4N)(2)[Mo6O18(NAr)] (Ar = 2-CH3-4-BrC6H3 (1) or 2,6-CH3-4-BrC6H2 (2)) have been synthesized via the DCC dehydrating protocol of the reaction of [alpha-Mo8O26](4-) with 2-methyl-4-bromoaniline hydrochloride or 2,6-dimethyl-4-bromoaniline hydrochloride in anhydrous Acetonitrile, which have been characterized by UV-Vis spectra, H-1 NMR, IR, cyclic voltarnmetry and X-ray single-crystal diffraction study. Both compounds crystallize in the monoclinic space group P (1) over bar, which are featured in a terminal phenylimido group linked to a Mo atom of a hexamolybdate cluster by a Mo-N triple bond. Interestingly, there are two conformational isomers of the cluster anions of 1 and 2 in the crystals. By cyclic voltammetry study, their special redox properties were also found in the end. (C) 2007 Elsevier B.V. All rights reserved.
语种	英语 ; 英语
出版者	ELSEVIER SCIENCE SA ; LAUSANNE ; PO BOX 564, 1001 LAUSANNE, SWITZERLAND
内容类型	期刊论文
源URL	[http://hdl.handle.net/123456789/12927]
专题	清华大学
推荐引用方式 GB/T 7714	Li, Qiang,Zhu, Li,Meng, Xianggao,et al. Two new bromo-functionalized organoimido derivatives of hexamolybdate: Synthesis, crystal structure, spectroscopic and electrochemical studies[J],2010, 2010.
APA	Li, Qiang,Zhu, Li,Meng, Xianggao,Zhu, Yulin,Hao, Jian,&Wei, Yongge.(2010).Two new bromo-functionalized organoimido derivatives of hexamolybdate: Synthesis, crystal structure, spectroscopic and electrochemical studies..
MLA	Li, Qiang,et al."Two new bromo-functionalized organoimido derivatives of hexamolybdate: Synthesis, crystal structure, spectroscopic and electrochemical studies".(2010).

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