Use of carbonaceous polysaccharide microspheres as templates for fabricating metal oxide hollow spheres | |
Sun, XM ; Liu, JF ; Li, YD | |
2010-05-06 ; 2010-05-06 | |
关键词 | hollow spheres metal oxides nanostructures recovery time sensors template synthesis CORE-SHELL NANOPARTICLES COLLOIDAL SPHERES GAS SENSORS PARTICLES TIO2 SNO2 NANOCRYSTALS AG-AT-TIO2 CRYSTALS SILICA Chemistry, Multidisciplinary |
中文摘要 | A general method for the synthesis of metal oxide hollow spheres has been developed by using carbonaceous polysaccharide microspheres prepared from saccharide solution as templates. Hollow spheres of a series of metal oxides (SnO2, Al2O3, Ga2O3, CoO, NiO, Mn3O4, Cr2O3, La2O3, Y2O3, Lu2O3, CeO2, TiO2, and ZrO2) have been prepared in this way. The method involves the initial absorption of metal ions from solution into the functional surface layer of carbonaceous saccharide microspheres; these are then densified and cross-linked in a subsequent films or cheese-like nanostructures of oxides can also be prepared by slightly modified procedures. XRD, TEM, HRTEM, and SAED have been used to characterize the structures. In a preliminary study on the gas sensitivity of SnO2 hollow spheres, considerably reduced "recovery times" were noted, exemplifying the distinct properties imparted by the hollow structure. These hollow or porous nanostructures have the potential for diverse applications, such as in gas sensitivity or catalysis, or as advanced ceramic materials. |
语种 | 英语 ; 英语 |
出版者 | WILEY-V C H VERLAG GMBH ; WEINHEIM ; PO BOX 10 11 61, D-69451 WEINHEIM, GERMANY |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/12379] |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Sun, XM,Liu, JF,Li, YD. Use of carbonaceous polysaccharide microspheres as templates for fabricating metal oxide hollow spheres[J],2010, 2010. |
APA | Sun, XM,Liu, JF,&Li, YD.(2010).Use of carbonaceous polysaccharide microspheres as templates for fabricating metal oxide hollow spheres.. |
MLA | Sun, XM,et al."Use of carbonaceous polysaccharide microspheres as templates for fabricating metal oxide hollow spheres".(2010). |
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