Transformation of Dipeptide-Based Organogels into Chiral Crystals by Cryogenic Treatment
Liu, Xingcen1,4; Fei, Jinbo1; Wang, Anhe2; Cui, Wei1; Zhu, Pengli3; Li, Junbai1,4
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2017-03-01
卷号56期号:10页码:2660-2663
关键词cryogenic treatment crystalline compounds dipeptides organogels self-assembly
ISSN号1433-7851
英文摘要Controlled molecular assembly is an important approach for the synthesis of single-component materials with diverse functions. Unlike traditional heat treatment or solvent modulation, cryogenic treatment at 77 K enabled the tunable transition of a self-assembled diphenylalanine organogel into a hexagonal crystal. Under these conditions, the assembled molecules undergo an internal rearrangement in the solid state to form a well-defined chiral crystal structure. Moreover, these assemblies exhibit enhanced emission. This strategy for the synthesis of single-component supramolecular assemblies can create new functions by manipulating phase transitions.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]ASSEMBLED PEPTIDE NANOTUBES ; PHASE ; GELS ; TRANSITION ; SOLVENT ; CRYSTALLIZATION ; NANOSTRUCTURES ; GELATION ; MICROTUBES ; MOLECULES
收录类别SCI
语种英语
WOS记录号WOS:000395183600018
内容类型期刊论文
源URL[http://ir.ipe.ac.cn/handle/122111/21949]  
专题过程工程研究所_生化工程国家重点实验室
作者单位1.Chinese Acad Sci, Inst Chem, BNLMS, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen 518055, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Liu, Xingcen,Fei, Jinbo,Wang, Anhe,et al. Transformation of Dipeptide-Based Organogels into Chiral Crystals by Cryogenic Treatment[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(10):2660-2663.
APA Liu, Xingcen,Fei, Jinbo,Wang, Anhe,Cui, Wei,Zhu, Pengli,&Li, Junbai.(2017).Transformation of Dipeptide-Based Organogels into Chiral Crystals by Cryogenic Treatment.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(10),2660-2663.
MLA Liu, Xingcen,et al."Transformation of Dipeptide-Based Organogels into Chiral Crystals by Cryogenic Treatment".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.10(2017):2660-2663.
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