Transformation of Dipeptide-Based Organogels into Chiral Crystals by Cryogenic Treatment | |
Liu, Xingcen1,4; Fei, Jinbo1; Wang, Anhe2; Cui, Wei1; Zhu, Pengli3; Li, Junbai1,4 | |
刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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2017-03-01 | |
卷号 | 56期号:10页码:2660-2663 |
关键词 | cryogenic treatment crystalline compounds dipeptides organogels self-assembly |
ISSN号 | 1433-7851 |
英文摘要 | Controlled molecular assembly is an important approach for the synthesis of single-component materials with diverse functions. Unlike traditional heat treatment or solvent modulation, cryogenic treatment at 77 K enabled the tunable transition of a self-assembled diphenylalanine organogel into a hexagonal crystal. Under these conditions, the assembled molecules undergo an internal rearrangement in the solid state to form a well-defined chiral crystal structure. Moreover, these assemblies exhibit enhanced emission. This strategy for the synthesis of single-component supramolecular assemblies can create new functions by manipulating phase transitions. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Multidisciplinary |
研究领域[WOS] | Chemistry |
关键词[WOS] | ASSEMBLED PEPTIDE NANOTUBES ; PHASE ; GELS ; TRANSITION ; SOLVENT ; CRYSTALLIZATION ; NANOSTRUCTURES ; GELATION ; MICROTUBES ; MOLECULES |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000395183600018 |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/21949] ![]() |
专题 | 过程工程研究所_生化工程国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Inst Chem, BNLMS, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen 518055, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Xingcen,Fei, Jinbo,Wang, Anhe,et al. Transformation of Dipeptide-Based Organogels into Chiral Crystals by Cryogenic Treatment[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(10):2660-2663. |
APA | Liu, Xingcen,Fei, Jinbo,Wang, Anhe,Cui, Wei,Zhu, Pengli,&Li, Junbai.(2017).Transformation of Dipeptide-Based Organogels into Chiral Crystals by Cryogenic Treatment.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(10),2660-2663. |
MLA | Liu, Xingcen,et al."Transformation of Dipeptide-Based Organogels into Chiral Crystals by Cryogenic Treatment".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.10(2017):2660-2663. |
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