Optical and Scintillation Properties of Cs2LiYCl6:Ce Crystal
Wang Qing-Qing1,2; Shi Jian2; Li Huan-Ying2; Chen Xiao-Feng2; Pan Shang-Ke3; Bian Jian-Jiang1; Ren Guo-Hao2
刊名JOURNAL OF INORGANIC MATERIALS
2017-02-01
卷号32期号:2页码:175-179
关键词Cs2LiYCl6:Ce crystal vertical Bridgement method crystal structure scintillation property
英文摘要Crystal structure of Cs2LiY0.95Cl6:5%Ce crystal (CYLC): grown by vertical Bridgement method from polycrystal raw materials was measured by X-ray diffraction (XRD) and was proved to have elpasolite structure. The detected structure of Cs2LiYCl6:Ce crystal was agreed well with theoretical structure. Six optical absorption bands which are suggested to originate from the transition of electron from 4f to 5d(1 similar to 5) of Ce ions and self-trapped excition (STE), can be identified in the absorption spectra of the CLYC:Ce crystal. X-ray and ultraviolet excited luminescence spectra of Cs2LiY0.95Cl6:5%Ce crystal present an emission band from 350 nm to 450 nm corresponding to 5d-4f transitions of Ce3+ ions. The peaks locating at 300 nm and 321 nm can be ascribed to core to valence luminescence and STE luminescence. Under the excitation of gamma-rays from Cs-137, Cs2LiY0.95Cl6:5%Ce crystal presents energy resolution of 8.1%, and scintillation decay time of 58 ns and 580 ns. All of these properties show that Cs2LiYCl6:Ce crystal is a promising scintillator for neutron and gamma detection applications.
WOS标题词Science & Technology ; Technology
类目[WOS]Materials Science, Ceramics
研究领域[WOS]Materials Science
关键词[WOS]GROWTH ; PURE
收录类别SCI
语种英语
WOS记录号WOS:000394920800010
内容类型期刊论文
源URL[http://ir.sic.ac.cn/handle/331005/23710]  
专题上海硅酸盐研究所_中试基地_期刊论文
作者单位1.Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200444, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 201800, Peoples R China
3.Ningbo Univ, Sch Mat Sci & Chem Engn, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Peoples R China
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GB/T 7714
Wang Qing-Qing,Shi Jian,Li Huan-Ying,et al. Optical and Scintillation Properties of Cs2LiYCl6:Ce Crystal[J]. JOURNAL OF INORGANIC MATERIALS,2017,32(2):175-179.
APA Wang Qing-Qing.,Shi Jian.,Li Huan-Ying.,Chen Xiao-Feng.,Pan Shang-Ke.,...&Ren Guo-Hao.(2017).Optical and Scintillation Properties of Cs2LiYCl6:Ce Crystal.JOURNAL OF INORGANIC MATERIALS,32(2),175-179.
MLA Wang Qing-Qing,et al."Optical and Scintillation Properties of Cs2LiYCl6:Ce Crystal".JOURNAL OF INORGANIC MATERIALS 32.2(2017):175-179.
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