Direct View for the Deformation Evolution of Sulfur Electrode during Li-S Battery Cycling
Wang Yu-Hui1,2; Jin Jun2; Guo Zhan-Sheng1; Wen Zhao-Yin2
刊名JOURNAL OF INORGANIC MATERIALS
2017-03-01
卷号32期号:3页码:247-251
关键词lithium-sulfur battery bending deformation electrode expansion transparent battery sulfur electrode
英文摘要An experimental set-up was developed which can observe electrode deformation and electrochemical reaction in-situ during the charge-discharge cycling of lithium-sulfur battery. The positive bending deformation during charge and discharge was monitored at real time. It was found that the positive curvature increased during discharge and reduced during open circuit. The curvature would recover the original state during charge period. As electrochemical reaction proceeds, the electrolyte near positive electrode gradually become yellow and deepened due to polysulfide dissolution of discharge products. Results of surface and section morphology observation on sulfur electrode before and after cycle using scanning electron microscope (SEM) were consistent with curvature changes during cycling and verified the volumetric expansion of sulfur electrode.
WOS标题词Science & Technology ; Technology
类目[WOS]Materials Science, Ceramics
研究领域[WOS]Materials Science
关键词[WOS]MESOPOROUS CARBON/SULFUR COMPOSITE ; LITHIUM BATTERIES ; CATHODE ; SHUTTLE ; PERFORMANCE ; DISCHARGE ; CHARGE
收录类别SCI
语种英语
WOS记录号WOS:000398243400004
内容类型期刊论文
源URL[http://ir.sic.ac.cn/handle/331005/23668]  
专题上海硅酸盐研究所_能量转换材料重点实验室_期刊论文
作者单位1.Shanghai Univ, Shanghai Inst Appl Math & Mech, Shanghai 200072, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China
推荐引用方式
GB/T 7714
Wang Yu-Hui,Jin Jun,Guo Zhan-Sheng,et al. Direct View for the Deformation Evolution of Sulfur Electrode during Li-S Battery Cycling[J]. JOURNAL OF INORGANIC MATERIALS,2017,32(3):247-251.
APA Wang Yu-Hui,Jin Jun,Guo Zhan-Sheng,&Wen Zhao-Yin.(2017).Direct View for the Deformation Evolution of Sulfur Electrode during Li-S Battery Cycling.JOURNAL OF INORGANIC MATERIALS,32(3),247-251.
MLA Wang Yu-Hui,et al."Direct View for the Deformation Evolution of Sulfur Electrode during Li-S Battery Cycling".JOURNAL OF INORGANIC MATERIALS 32.3(2017):247-251.
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