Hybrid films of VO2 nanoparticles and a nickel(II)-based ligand exchange thermochromic system: excellent optical performance with a temperature responsive colour change

CORC > 上海硅酸盐研究所 > 中国科学院上海硅酸盐研究所 > 古陶瓷与工业陶瓷工程研究中心 > 期刊论文

	Hybrid films of VO2 nanoparticles and a nickel(II)-based ligand exchange thermochromic system: excellent optical performance with a temperature responsive colour change
	Zhu, Jingting 1,2; Huang, Aibin 1,2; Ma, Haibin 1,2; Chen, Yunxiang 1,2; Zhang, Sanpei 1,2; Ji, Shidong 1; Bao, Shanhu 1; Jin, Ping 1,3
刊名	NEW JOURNAL OF CHEMISTRY
	2017
卷号	41 期号:2 页码:830-835
英文摘要	It is well known that excellent optical performance is a vital factor of vanadium dioxide (VO2) thermochromic films. Except for optimizing the properties of VO2 itself as most researchers have been focusing on, hybridizing has been verified to be an effective way to substantially improve the solar regulation efficiency (Delta T-sol) and luminous transmittance (T-lum) of the thermochromic films. Therefore, a nickel(II)based ligand exchange thermochromic system (NLETS), which contains nickel(II), 2,2-dimethylpropane-1,3-diol ((CH3)(2)C(CH2OH)(2)) and bromide, is selected in this paper to be combined with VO2 nanoparticles forming a hybrid film. Compared with a pure VO2 film, this novel scheme demonstrates a 127% increase (from 8.02% to 18.19%) in Delta T-sol at a rather high T-lum (T-lum,T- l = 73.36% and T-lum,T- h = 68.71%). What is more, since the intrinsic colour change of the NLETS from colourless to blue, the hybrid film presents an evident temperature responsive colour change: from yellow to green, which is crucial for exhibition, publicity and promotion of thermochromic products.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	ENHANCED LUMINOUS TRANSMITTANCE ; METAL-INSULATOR-TRANSITION ; DOPED VANADIUM DIOXIDE ; SOLAR MODULATION ; PHASE-TRANSITION ; VISIBLE TRANSMITTANCE ; SMART ; WINDOW ; FOILS ; OPTIMIZATION
收录类别	SCI
语种	英语
WOS记录号	WOS:000393887200049
内容类型	期刊论文
源URL	[http://ir.sic.ac.cn/handle/331005/23469]
专题	上海硅酸盐研究所_古陶瓷与工业陶瓷工程研究中心_期刊论文
作者单位	1.Chinese Acad Sci, Shanghai Inst Ceram, Dingxi 1295, Shanghai 200050, Peoples R China 2.Univ Chinese Acad Sci, Yuquan 19, Beijing 100049, Peoples R China 3.Natl Inst Adv Ind Sci & Technol, Moriyama Ku, Nagoya, Aichi 4638560, Japan
推荐引用方式 GB/T 7714	Zhu, Jingting,Huang, Aibin,Ma, Haibin,et al. Hybrid films of VO2 nanoparticles and a nickel(II)-based ligand exchange thermochromic system: excellent optical performance with a temperature responsive colour change[J]. NEW JOURNAL OF CHEMISTRY,2017,41(2):830-835.
APA	Zhu, Jingting.,Huang, Aibin.,Ma, Haibin.,Chen, Yunxiang.,Zhang, Sanpei.,...&Jin, Ping.(2017).Hybrid films of VO2 nanoparticles and a nickel(II)-based ligand exchange thermochromic system: excellent optical performance with a temperature responsive colour change.NEW JOURNAL OF CHEMISTRY,41(2),830-835.
MLA	Zhu, Jingting,et al."Hybrid films of VO2 nanoparticles and a nickel(II)-based ligand exchange thermochromic system: excellent optical performance with a temperature responsive colour change".NEW JOURNAL OF CHEMISTRY 41.2(2017):830-835.