Nitrogen-Doped Carbon Vesicles with Dual Iron-Based Sites for Efficient Oxygen Reduction

CORC > 上海硅酸盐研究所 > 中国科学院上海硅酸盐研究所 > 高性能陶瓷和超微结构国家重点实验室 > 期刊论文

	Nitrogen-Doped Carbon Vesicles with Dual Iron-Based Sites for Efficient Oxygen Reduction
	Li, Qianru 1,2; Wan, Gang 1,2; Zhao, Han 1,2; Pan, Linyu 1,2; Wang, Ning 1,2; Zhao, Wanpeng 1,2; Zhou, Xiaoxia 1,2; Cui, Xiangzhi 1,2; Chen, Hangrong 1,2
刊名	CHEMSUSCHEM
	2017-02-08
卷号	10 期号:3 页码:499-505
关键词	carbide electrocatalyst iron mesoporous oxygen reduction reaction
英文摘要	A nitrogen-doped vesicle-like porous carbon with well-integrated dual iron-based catalytic sites was developed through direct pyrolysis of inexpensive and abundant precursors. Benefiting from the mesoporous structures with synchronous construction of Fe-Nx and Fe/Fe3C@NC sites, the optimized catalyst exhibited outstanding performance for the oxygen reduction reaction (ORR) in alkaline media, even superior to the commercial Pt/C catalyst. Detailed characterizations revealed that Fe/Fe3C@NC sites can make major catalytic contributions in basic media, whereas the Fe-Nx sites were found to play an indispensable role for ORR in acidic media.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	MEMBRANE FUEL-CELLS ; ACTIVE-SITES ; TETRAMETHOXYPHENYL PORPHYRIN ; COMPOSITE ELECTROCATALYST ; METAL ELECTROCATALYST ; ENERGY-CONVERSION ; GRAPHITIC LAYERS ; CATHODE CATALYST ; PERFORMANCE ; GRAPHENE
收录类别	SCI
语种	英语
WOS记录号	WOS:000394572100005
内容类型	期刊论文
源URL	[http://ir.sic.ac.cn/handle/331005/23474]
专题	上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文
作者单位	1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, 1295 Ding Xi Rd, Shanghai 200050, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Li, Qianru,Wan, Gang,Zhao, Han,et al. Nitrogen-Doped Carbon Vesicles with Dual Iron-Based Sites for Efficient Oxygen Reduction[J]. CHEMSUSCHEM,2017,10(3):499-505.
APA	Li, Qianru.,Wan, Gang.,Zhao, Han.,Pan, Linyu.,Wang, Ning.,...&Chen, Hangrong.(2017).Nitrogen-Doped Carbon Vesicles with Dual Iron-Based Sites for Efficient Oxygen Reduction.CHEMSUSCHEM,10(3),499-505.
MLA	Li, Qianru,et al."Nitrogen-Doped Carbon Vesicles with Dual Iron-Based Sites for Efficient Oxygen Reduction".CHEMSUSCHEM 10.3(2017):499-505.