Aerobic dehydrogenation of cyclic ketones into corresponding phenols catalyzed by heterogeneous Pd nanocatalysts
Shah, Mazloom ; Guo, Qing-Xiang ; Fu, Yao
刊名CATALYSIS COMMUNICATIONS
2017
卷号89期号:x页码:60-63
关键词Palladium nanoparticles Heterogeneous catalysts Dehydrogenation Cyclic ketones Phenols
中文摘要The Pd, Ni, Ni-Sn, Cu and Ag@Pd nanocatalyst having different shape and size were used for direct dehydrogenation of cyclic ketones to the corresponding phenols in the presence of O-2 as the oxidant. Among all catalyst tested, metallic Pd-1 nanoparticles exhibited excellent catalytic performance both in presence and absence of p-toluenesulfonic acid. The dehydrogenation of cyclohexanone catalyzed by Pd-1 nanocatalyst led to a 93% yield of the desired cyclohexenone and phenol. X-ray diffraction (XRD) and transmission electron microscopy (TEM) confirmed that there was no change in morphology, crystal phases and particles size of Pd-1 nanocatalyst after the reaction.
语种英语
公开日期2017-03-08
内容类型期刊论文
源URL[http://ir.xtbg.org.cn/handle/353005/10309]  
专题西双版纳热带植物园_其他
推荐引用方式
GB/T 7714
Shah, Mazloom,Guo, Qing-Xiang,Fu, Yao. Aerobic dehydrogenation of cyclic ketones into corresponding phenols catalyzed by heterogeneous Pd nanocatalysts[J]. CATALYSIS COMMUNICATIONS,2017,89(x):60-63.
APA Shah, Mazloom,Guo, Qing-Xiang,&Fu, Yao.(2017).Aerobic dehydrogenation of cyclic ketones into corresponding phenols catalyzed by heterogeneous Pd nanocatalysts.CATALYSIS COMMUNICATIONS,89(x),60-63.
MLA Shah, Mazloom,et al."Aerobic dehydrogenation of cyclic ketones into corresponding phenols catalyzed by heterogeneous Pd nanocatalysts".CATALYSIS COMMUNICATIONS 89.x(2017):60-63.
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