Aerobic dehydrogenation of cyclic ketones into corresponding phenols catalyzed by heterogeneous Pd nanocatalysts | |
Shah, Mazloom ; Guo, Qing-Xiang ; Fu, Yao | |
刊名 | CATALYSIS COMMUNICATIONS |
2017 | |
卷号 | 89期号:x页码:60-63 |
关键词 | Palladium nanoparticles Heterogeneous catalysts Dehydrogenation Cyclic ketones Phenols |
中文摘要 | The Pd, Ni, Ni-Sn, Cu and Ag@Pd nanocatalyst having different shape and size were used for direct dehydrogenation of cyclic ketones to the corresponding phenols in the presence of O-2 as the oxidant. Among all catalyst tested, metallic Pd-1 nanoparticles exhibited excellent catalytic performance both in presence and absence of p-toluenesulfonic acid. The dehydrogenation of cyclohexanone catalyzed by Pd-1 nanocatalyst led to a 93% yield of the desired cyclohexenone and phenol. X-ray diffraction (XRD) and transmission electron microscopy (TEM) confirmed that there was no change in morphology, crystal phases and particles size of Pd-1 nanocatalyst after the reaction. |
语种 | 英语 |
公开日期 | 2017-03-08 |
内容类型 | 期刊论文 |
源URL | [http://ir.xtbg.org.cn/handle/353005/10309] |
专题 | 西双版纳热带植物园_其他 |
推荐引用方式 GB/T 7714 | Shah, Mazloom,Guo, Qing-Xiang,Fu, Yao. Aerobic dehydrogenation of cyclic ketones into corresponding phenols catalyzed by heterogeneous Pd nanocatalysts[J]. CATALYSIS COMMUNICATIONS,2017,89(x):60-63. |
APA | Shah, Mazloom,Guo, Qing-Xiang,&Fu, Yao.(2017).Aerobic dehydrogenation of cyclic ketones into corresponding phenols catalyzed by heterogeneous Pd nanocatalysts.CATALYSIS COMMUNICATIONS,89(x),60-63. |
MLA | Shah, Mazloom,et al."Aerobic dehydrogenation of cyclic ketones into corresponding phenols catalyzed by heterogeneous Pd nanocatalysts".CATALYSIS COMMUNICATIONS 89.x(2017):60-63. |
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