Crystal Growth and Characterization of the Rare-earth Orthoferrite Sm0.8Tb0.2FeO3 Single Crystal
Zhao Xiang-Yang1; Man Pei-Wen1; Xie Tao2; Wu An-Hua1; Su Liang-Bi1
刊名JOURNAL OF INORGANIC MATERIALS
2016-09-20
卷号31期号:9页码:1004-1008
关键词orthoferrites floating zone method phase transitions
英文摘要Sm0.8Tb0.2FeO3 single crystal was grown by the floating zone method. Laue back reflection was used to check the crystal's quality and orientation. The temperature dependence of the magnetization under ZFC process was measured in an external field 500 Oe along c-axis. A clear spin reorientation is observed in the range of 360-400 K. Considering the recent report that the spin reorientation transition temperature of Sm1-xTbxFeO3 is linear decreased with the increase of Tb ions content, the present data reveals the changed Fe3+-Re3+ super-exchange interaction. The curve of temperature dependence of thermal expansion exhibits three phase transitions at about 250 K, 350-480 K, and 700 K, respectively. The abnormal phase transition observed at 250 K may be resulted from the change of rare earth ions moment orientation polarized by Fe3+ sub-lattice net moment. The spin reorientation transition takes place in a temperature range from 350 K to 480 K. The iron spins transform from antiferromagnetic ordered arrangement to paramagnetic disordered arrangement at similar to 700 K.
WOS标题词Science & Technology ; Technology
类目[WOS]Materials Science, Ceramics
研究领域[WOS]Materials Science
关键词[WOS]MAGNETIC-PROPERTIES ; WEAK FERROMAGNETISM ; SPIN-REORIENTATION ; TEMPERATURE ; ANISOTROPY ; FERRITE ; TBFEO3
收录类别SCI
语种英语
WOS记录号WOS:000383397000017
内容类型期刊论文
源URL[http://ir.sic.ac.cn/handle/331005/22826]  
专题上海硅酸盐研究所_人工晶体研究中心_期刊论文
作者单位1.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
2.Shanghai Inst Technol, Sch Mat Sci & Engn, Shanghai 200235, Peoples R China
推荐引用方式
GB/T 7714
Zhao Xiang-Yang,Man Pei-Wen,Xie Tao,et al. Crystal Growth and Characterization of the Rare-earth Orthoferrite Sm0.8Tb0.2FeO3 Single Crystal[J]. JOURNAL OF INORGANIC MATERIALS,2016,31(9):1004-1008.
APA Zhao Xiang-Yang,Man Pei-Wen,Xie Tao,Wu An-Hua,&Su Liang-Bi.(2016).Crystal Growth and Characterization of the Rare-earth Orthoferrite Sm0.8Tb0.2FeO3 Single Crystal.JOURNAL OF INORGANIC MATERIALS,31(9),1004-1008.
MLA Zhao Xiang-Yang,et al."Crystal Growth and Characterization of the Rare-earth Orthoferrite Sm0.8Tb0.2FeO3 Single Crystal".JOURNAL OF INORGANIC MATERIALS 31.9(2016):1004-1008.
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