Enhanced cycle performance of a Na/NiCl2 battery based on Ni particles encapsulated with Ni3S2 layer
Ao, Xin1,2; Wen, Zhaoyin1,2; Hu, Yingying1; Wu, Tian1,2; Wu, Xiangwei1; He, Qiming1,2
刊名JOURNAL OF POWER SOURCES
2017-02-01
卷号340页码:411-418
关键词Ni3S2 surface layer Sodium-nickel chloride battery Zebra battery Ni particle growth Cell cycling behavior
英文摘要Nickel particles with different contents of Ni3S2 surface layer were prepared for their application as cathode materials in Na/NiCl2 batteries. The surface modification of nickel particles is found to prevent their growth and battery degradation during cycling. The optimum level of surface modification was determined by electrochemical tests and morphology characterization. Excessive Ni3S2 layer seems to cause particle aggregation resulting in low reversible capacity. The capacity of the cell with optimum level of Ni3S2 surface modification layer after 50 cycles is about 4 times greater than that without Ni3S2 surface modification layer. (C) 2016 Elsevier B.V. All rights reserved.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science
关键词[WOS]ZEBRA BATTERY ; HIGH-TEMPERATURE ; BETA-ALUMINA ; NICKEL ; CELL ; SYSTEM ; DEGRADATION ; CHALLENGES ; ELECTRODES
收录类别SCI
语种英语
WOS记录号WOS:000392771900047
内容类型期刊论文
源URL[http://ir.sic.ac.cn/handle/331005/23407]  
专题上海硅酸盐研究所_能量转换材料重点实验室_期刊论文
作者单位1.Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, 1295 DingXi Rd, Shanghai 200050, Peoples R China
2.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Ao, Xin,Wen, Zhaoyin,Hu, Yingying,et al. Enhanced cycle performance of a Na/NiCl2 battery based on Ni particles encapsulated with Ni3S2 layer[J]. JOURNAL OF POWER SOURCES,2017,340:411-418.
APA Ao, Xin,Wen, Zhaoyin,Hu, Yingying,Wu, Tian,Wu, Xiangwei,&He, Qiming.(2017).Enhanced cycle performance of a Na/NiCl2 battery based on Ni particles encapsulated with Ni3S2 layer.JOURNAL OF POWER SOURCES,340,411-418.
MLA Ao, Xin,et al."Enhanced cycle performance of a Na/NiCl2 battery based on Ni particles encapsulated with Ni3S2 layer".JOURNAL OF POWER SOURCES 340(2017):411-418.
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