One-Step Hydrothermal Synthesis of TiO2@MoO3 Core-Shell Nanomaterial: Microstructure, Growth Mechanism, and Improved Photochromic Property

CORC > 上海硅酸盐研究所 > 中国科学院上海硅酸盐研究所 > 古陶瓷与工业陶瓷工程研究中心 > 期刊论文

	One-Step Hydrothermal Synthesis of TiO2@MoO3 Core-Shell Nanomaterial: Microstructure, Growth Mechanism, and Improved Photochromic Property
	Li, Ning 1; Li, Yamei 2; Li, Wenjing 1; Ji, Shidong 1; Jin, Ping 1,3
刊名	JOURNAL OF PHYSICAL CHEMISTRY C
	2016-02-18
卷号	120 期号:6 页码:3341-3349
英文摘要	Photochromic TiO2@MoO3 core-shell (TM) nano powder was synthesized by a one-step hydrothermal method and characterized with XRD, TEM, Raman, and a spectrophotometer. The nanopowder has a very small particle size of 5-10 nm in diameter, and a well-defined core shell structure with the tight interface; that is, an anatase TiO2 core is tightly surrounded with amorphous MoO3, to form an ideal heterojunction structure. The growth mechanism was proposed with a surface-induced nucleation of amorphous MoO3 from a well-mixed precursor, where the mutual inhibition between core and shell led to the confined core size. The photochromic performance of TiO2@MoO3 was evaluated in solution as well as casted thin film on glass using a spectrophotometer, with a comparison to that of single MoO3. A significant enhancement in the photochromic properties was demonstrated for TM; that is, the change of the absorbance in water at 600 nm is about 30 times larger than that of alpha-MoO3, and a 20% transmittance regulation at 500-800 nm was obtained for the TM-based thin film. Meanwhile, the samples in ethanol showed much stronger photochromic coloration efficiency than that in water by 66.6% enhancement in the absorption at 600 nm. Such a significant photochromic enhancement is considered to the formation of a relatively ideal heterojunction at the interface, leading to an efficient electron hole separation. The size effect of TM provides a high specific surface area for cation insertion/extraction and diffusion" and decreases the distance of electron transfer. Furthermore, a shift of excitation wavelengths from UV to visible was also observed due to the appearance of extra defect bands by Mo doping, into TiO2 in their interface, which was supported by XRD and Raman measurements. The enhanced photochromic performance of TiO2@MoO3 is expected to be used for color displays and smart windows.
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
研究领域[WOS]	Chemistry ; Science & Technology - Other Topics ; Materials Science
关键词[WOS]	ENHANCED PHOTOCATALYTIC PROPERTIES ; OXIDE THIN-FILMS ; VISIBLE-LIGHT ; RAMAN-SPECTROSCOPY ; METHYLENE-BLUE ; TIO2 NANOTUBES ; METAL OXIDES ; MOO3 ; WO3 ; NANOCRYSTALS
收录类别	SCI
语种	英语
WOS记录号	WOS:000370678700029
内容类型	期刊论文
源URL	[http://ir.sic.ac.cn/handle/331005/23209]
专题	上海硅酸盐研究所_古陶瓷与工业陶瓷工程研究中心_期刊论文
作者单位	1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Dingxi 1295, Shanghai 200050, Peoples R China 2.RIKEN, Biofunct Catalyst Res Team, 2-1 Hirosawa, Wako, Saitama 3510198, Japan 3.Natl Inst Adv Ind Sci & Technol, Moriyama Ku, Nagoya, Aichi 4638560, Japan
推荐引用方式 GB/T 7714	Li, Ning,Li, Yamei,Li, Wenjing,et al. One-Step Hydrothermal Synthesis of TiO2@MoO3 Core-Shell Nanomaterial: Microstructure, Growth Mechanism, and Improved Photochromic Property[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2016,120(6):3341-3349.
APA	Li, Ning,Li, Yamei,Li, Wenjing,Ji, Shidong,&Jin, Ping.(2016).One-Step Hydrothermal Synthesis of TiO2@MoO3 Core-Shell Nanomaterial: Microstructure, Growth Mechanism, and Improved Photochromic Property.JOURNAL OF PHYSICAL CHEMISTRY C,120(6),3341-3349.
MLA	Li, Ning,et al."One-Step Hydrothermal Synthesis of TiO2@MoO3 Core-Shell Nanomaterial: Microstructure, Growth Mechanism, and Improved Photochromic Property".JOURNAL OF PHYSICAL CHEMISTRY C 120.6(2016):3341-3349.