Effect of incorporation manner of Zr on the Co/SBA-15 catalyst for the Fischer-Tropsch synthesis

CORC > 青岛生物能源与过程研究所 > 中国科学院青岛生物能源与过程研究所 > 热化学转化事业部

	Effect of incorporation manner of Zr on the Co/SBA-15 catalyst for the Fischer-Tropsch synthesis
	Li, Zhuo 1,2; Wu, Jinhu 2; Yu, Jianqiang 1; Han, Dezhi 2; Wu, Liyang 2; Li, Jianqing 2
刊名	JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
	2016-12-01
卷号	424 页码:384-392
关键词	Fischer-Tropsch synthesis Co/SBA-15 Zirconium Hydrocarbons selectivity Chain growth probability
英文摘要	The effect of incorporation manner of Zr on the textural properties, surface physicochemical properties, reduction degree and catalytic performance of Co/SBA-15 catalyst for the Fischer-Tropsch synthesis (FTS) was investigated. The catalysts were prepared by sequential impregnation, co-impregnation and in situ synthesis method, respectively. The loading amount of Co and Zr remained constant in all catalysts with 15 wt.% and 5 wt.%, respectively. The catalysts were characterized by N-2 adsorption-desorption, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), temperature-programmed reduction (H-2-TPR) and evaluated for the FTS. It was revealed that the Co3O4 was considered as the main surface cobalt phase, and the BET surface area and pore size were decreased regardless of the incorporation manner. The reduction degree of cobalt species increased from 80% (Co/SBA-15) to 90% (Co/Zr/SBA-1.5) and 85% (CoZr/SBA-15) with the addition of Zr, except for the Co/Zr-SBA-15 catalyst (74%). The catalyst prepared by sequential impregnation method (Co/Zr/SBA-15) showed the highest selectivity of long-chain hydrocarbons (C-12-C-22, 53%) with the chain growth probability a up to 0.84, which could be attributed to the highest reducibility of cobalt species. (C) 2016 Published by Elsevier B.V.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical
研究领域[WOS]	Chemistry
关键词[WOS]	ZIRCONIA-MODIFIED ALUMINA ; COBALT CATALYSTS ; CO HYDROGENATION ; PORE STRUCTURE ; SUPPORTED CO ; PROMOTERS ; SIZE ; REDUCIBILITY ; SELECTIVITY ; DISPERSION
收录类别	SCI
语种	英语
WOS记录号	WOS:000386739300043
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/9211]
专题	青岛生物能源与过程研究所_热化学转化事业部
作者单位	1.Qingdao Univ, Collaborat Innovat Ctr Marine Biomass Fiber Mat &, Sch Chem & Chem Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Li, Zhuo,Wu, Jinhu,Yu, Jianqiang,et al. Effect of incorporation manner of Zr on the Co/SBA-15 catalyst for the Fischer-Tropsch synthesis[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2016,424:384-392.
APA	Li, Zhuo,Wu, Jinhu,Yu, Jianqiang,Han, Dezhi,Wu, Liyang,&Li, Jianqing.(2016).Effect of incorporation manner of Zr on the Co/SBA-15 catalyst for the Fischer-Tropsch synthesis.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,424,384-392.
MLA	Li, Zhuo,et al."Effect of incorporation manner of Zr on the Co/SBA-15 catalyst for the Fischer-Tropsch synthesis".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 424(2016):384-392.