Self-assembly of achiral monomer into left-handed helical polyanthracene nanofibers

CORC > 苏州纳米技术与纳米仿生研究所 > 中国科学院苏州纳米技术与纳米仿生研究所 > 纳米研究国际实验室 > 张珽团队

	Self-assembly of achiral monomer into left-handed helical polyanthracene nanofibers
	Han, B; Shen, FP; Su, H; Zhang, X; Shen, Y; Zhang, T(张珽)
刊名	MATERIALS EXPRESS
	2016
卷号	6 期号:1
通讯作者	Zhang, T(张珽) ; Shen, Y
英文摘要	Bionic control over the assembly of achiral molecules into chiral supramolecular architectures is challenging, and typically relies on preexisting templates. We demonstrated that anthracene monomers could self-assemble into polyanthracene (PA) nanofibers with well-defined left-handed helical nanoarchitectures under well-controlled conditions. The spontaneous formation of supramolecular helices might be ascribed to the steric constraints imposed by dehydrocyclization carried out at the 4,8 sites of the benzene ring of the anthracene monomer. Furthermore, high quality, few-layer graphene, derived from the chiral helical PA nanofibers, provided promising prospects and new ideas for functional materials synthesis and chirality amplification.
关键词[WOS]	POLYANILINE NANOFIBERS ; THIN-FILMS ; POLYMERIZATION ; ANTHRACENE ; GRAPHENE ; FABRICATION ; COLLOIDS ; COMPLEX ; SENSORS
收录类别	SCI ; EI
语种	英语
WOS记录号	WOS:000371194100012
内容类型	期刊论文
源URL	[http://ir.sinano.ac.cn/handle/332007/4872]
专题	苏州纳米技术与纳米仿生研究所_纳米研究国际实验室_张珽团队
推荐引用方式 GB/T 7714	Han, B,Shen, FP,Su, H,et al. Self-assembly of achiral monomer into left-handed helical polyanthracene nanofibers[J]. MATERIALS EXPRESS,2016,6(1).
APA	Han, B,Shen, FP,Su, H,Zhang, X,Shen, Y,&Zhang, T.(2016).Self-assembly of achiral monomer into left-handed helical polyanthracene nanofibers.MATERIALS EXPRESS,6(1).
MLA	Han, B,et al."Self-assembly of achiral monomer into left-handed helical polyanthracene nanofibers".MATERIALS EXPRESS 6.1(2016).