Facile synthesis of Zn2Ti3O8 hollow spheres based on ion exchange as promising anodes for lithium ion batteries

CORC > 苏州纳米技术与纳米仿生研究所 > 中国科学院苏州纳米技术与纳米仿生研究所 > 纳米研究国际实验室 > 蔺洪振团队

	Facile synthesis of Zn2Ti3O8 hollow spheres based on ion exchange as promising anodes for lithium ion batteries
	Liao, WM; Tian, JH; Shan, ZQ; Na, R; Cui, L; Lin, HZ(蔺洪振)
刊名	ELECTROCHIMICA ACTA
	2016
卷号	216
通讯作者	Cui, L
英文摘要	A new approach has been designed to convert typical Stober silica spheres to Zn2Ti3O8 (ZTO) hollow spheres with different shell thicknesses as anode materials for Lithium ion batteries. The morphologies, structures and synthesis process of ZTO hollow spheres are systematically investigated. X-ray diffraction (XRD) analysis shows that the good ZTO crystal is formed after being sintered at 500 degrees C for 2 h. The galvanostatic cycle tests exhibit excellent cycling stability, reversibility and low voltage. At a current density of 200 mA g(-1), the discharge specific capacities of 186.2 mAh g(-1), 173.6 mAh g(-1) and 169.9 mAh g(-1) have been achieved after 100 cycles, 200 cycles and 300 cycles, respectively. The superior electrochemical performance could be attributed to the hollow structure and characteristics of ZTO crystals. Cyclic voltammetry (CV) curves show symmetrical and stable redox peaks at 1.1 V and 1.5 V for ZTO hollow spheres after the first cycle. Electrochemical impedance spectroscopy (EIS) measurement analysis also indicates that ZTO hollow spheres as anode materials for LIBs have excellent electrochemical performance. (C) 2016 Published by Elsevier Ltd.
关键词[WOS]	RATE CAPABILITY ; LONG-LIFE ; STORAGE ; NANOCRYSTALS ; NANOSPHERES ; PERFORMANCE ; NANOFIBERS ; NANOSHEETS ; COMPOSITE ; ARRAYS
收录类别	SCI ; EI
语种	英语
WOS记录号	WOS:000385495000012
内容类型	期刊论文
源URL	[http://ir.sinano.ac.cn/handle/332007/4783]
专题	苏州纳米技术与纳米仿生研究所_纳米研究国际实验室_蔺洪振团队
推荐引用方式 GB/T 7714	Liao, WM,Tian, JH,Shan, ZQ,et al. Facile synthesis of Zn2Ti3O8 hollow spheres based on ion exchange as promising anodes for lithium ion batteries[J]. ELECTROCHIMICA ACTA,2016,216.
APA	Liao, WM,Tian, JH,Shan, ZQ,Na, R,Cui, L,&Lin, HZ.(2016).Facile synthesis of Zn2Ti3O8 hollow spheres based on ion exchange as promising anodes for lithium ion batteries.ELECTROCHIMICA ACTA,216.
MLA	Liao, WM,et al."Facile synthesis of Zn2Ti3O8 hollow spheres based on ion exchange as promising anodes for lithium ion batteries".ELECTROCHIMICA ACTA 216(2016).