Cu(OAc)(2)-Mediated Reaction of [60]Fullerene with Aldehydes and Primary Amines for the Synthesis of Fulleropyrrolines

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	Cu(OAc)(2)-Mediated Reaction of [60]Fullerene with Aldehydes and Primary Amines for the Synthesis of Fulleropyrrolines
	Wu, Jun 1,2; Liu, Chun-Xiang 1,2; Wang, Hui-Juan 3; Li, Fa-Bao 1,2; Shi, Ji-Long 1,2; Liu, Li 1,2; Li, Jia-Xing 4; Liu, Chao-Yang 3; Huang, Yong-Shun 4
刊名	JOURNAL OF ORGANIC CHEMISTRY
	2016-10-07
卷号	81 期号:19 页码:9296-9307
英文摘要	The facile one-step reaction of [60]fullerene with aldehydes and primary amines in the presence of cheap and easily available Cu(OAc)(2)center dot H2O afforded a series of new types of fulleropyrrolines with trisubstituted C=C bonds in good to excellent yields, which would be difficult to prepare by known methods. The formed fulleropyrroline under the assistance of Pd(OAc)(2) and CuCl2 center dot 2H(2)O could be further converted to 1-fulleropyrrolidine by the chlorohydroxylation reaction of C=C bond. Subsequent elimination reaction of 1-fulleropyrrolidine with the aid of TsOH center dot H2O generated the scarce 1-fulleropyrroline derivative.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Organic
研究领域[WOS]	Chemistry
关键词[WOS]	ONE-STEP REACTION ; ASYMMETRIC CHLOROHYDRIN SYNTHESIS ; MANGANESE(III) ACETATE DIHYDRATE ; MEDIATED RADICAL REACTIONS ; FERRIC PERCHLORATE ; FACILE ACCESS ; 60 FULLERENE ; DERIVATIVES ; STEREOCHEMISTRY ; CHEMISTRY
收录类别	SCI
语种	英语
WOS记录号	WOS:000385054300059
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/9944]
专题	武汉物理与数学研究所_高技术创新与发展中心
作者单位	1.Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Peoples R China 2.Hubei Univ, Sch Chem & Chem Engn, Wuhan 430062, Peoples R China 3.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 4.Chinese Acad Sci, Inst Plasma Phys, Key Lab Novel Thin Film Solar Cells, POB 1126, Hefei 230031, Peoples R China
推荐引用方式 GB/T 7714	Wu, Jun,Liu, Chun-Xiang,Wang, Hui-Juan,et al. Cu(OAc)(2)-Mediated Reaction of [60]Fullerene with Aldehydes and Primary Amines for the Synthesis of Fulleropyrrolines[J]. JOURNAL OF ORGANIC CHEMISTRY,2016,81(19):9296-9307.
APA	Wu, Jun.,Liu, Chun-Xiang.,Wang, Hui-Juan.,Li, Fa-Bao.,Shi, Ji-Long.,...&Huang, Yong-Shun.(2016).Cu(OAc)(2)-Mediated Reaction of [60]Fullerene with Aldehydes and Primary Amines for the Synthesis of Fulleropyrrolines.JOURNAL OF ORGANIC CHEMISTRY,81(19),9296-9307.
MLA	Wu, Jun,et al."Cu(OAc)(2)-Mediated Reaction of [60]Fullerene with Aldehydes and Primary Amines for the Synthesis of Fulleropyrrolines".JOURNAL OF ORGANIC CHEMISTRY 81.19(2016):9296-9307.