Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 中国科学院特殊环境功能材料与器件重点试验室

	Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method
	Shi, GQ (Shi, Guoqiang); Zhang, FF (Zhang, Fangfang); Zhang, BB (Zhang, Bingbing); Hou, DW (Hou, Dianwei); Chen, XL (Chen, Xinglong); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
刊名	INORGANIC CHEMISTRY
	2017
卷号	56 期号:1 页码:344-350
通讯作者	Zhang, FF
英文摘要	As important materials in modulating the polarization of light, birefringent crystals have attracted considerable attention and played crucial roles in the field of optical communication and the laser industry. Limited by the transparency range, few birefringent crystals can be used in the deep-ultraviolet (DUV) region, except for alpha-BaB2O4 (alpha-BBO) However, the application of a-BBO in the DUV range is restricted by the relatively high cutoff edge and low transmittance rate below 200 nm. In this paper, we design and synthesize a new fluoroborate, Na2B6O9F2, by introducing fluorine into borate system. It possesses a short cutoff edge of 169 nm and birefringence larger than 0.080 at 589.3 nm. The Na2B6O9F2 crystals with sizes up to 3.0 mm x 1.5 mm X 0.2 mm have been grown with good quality by a high-temperature solution method in the open system. First principles calculations were carried out to understand the optical properties.
收录类别	SCI
WOS记录号	WOS:000391248900040
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/4723]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室新疆理化技术研究所_材料物理与化学研究室
作者单位	1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Shi, GQ ,Zhang, FF ,Zhang, BB ,et al. Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method[J]. INORGANIC CHEMISTRY,2017,56(1):344-350.
APA	Shi, GQ .,Zhang, FF .,Zhang, BB .,Hou, DW .,Chen, XL .,...&Pan, SL .(2017).Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method.INORGANIC CHEMISTRY,56(1),344-350.
MLA	Shi, GQ ,et al."Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method".INORGANIC CHEMISTRY 56.1(2017):344-350.