Bi3+-doped CH3NH3PbI3: Red-shifting absorption edge and longer charge carrier lifetime

CORC > 上海硅酸盐研究所 > 中国科学院上海硅酸盐研究所 > 能量转换材料重点实验室 > 期刊论文

	Bi3+-doped CH3NH3PbI3: Red-shifting absorption edge and longer charge carrier lifetime
	Wang, Ruiqi 1,2; Zhang, Xian 1,2; He, Jianqiao 3,4; Ma, Cheng 1,2; Xu, Li 5; Sheng, Peng 5; Huang, Fuqiang 1,2,3,4
刊名	JOURNAL OF ALLOYS AND COMPOUNDS
	2017-02-25
卷号	695 页码:555-560
关键词	Hybrid perovskite Doping Band gap energy Charge carrier lifetime
英文摘要	Ion doping is an effective approach to improve the properties of hybrid perovskite CH3NH3PbI3, such as chemical stability and solar absorption. Here Bi3+-doped CH3NH3PbI3 was synthesized via cooling crystallization process in aqueous solution. Along with the Bi3+-doping, the bandgap of CH3NH3PbI3 could be significantly narrowed, by the maximum value of 140 meV at the optimal doping level of 1.6 M %. Transient photovoltage measurement (TPV) revealed the Bi3+-doped CH3NH3PbI3 could achieve a charge carrier lifetime of 280 ms, which was almost twice longer than that of pristine CH3NH3PbI3 (157 ms). The prolonged carrier lifetime of Bi3+-doped CH3NH3PbI3 was supposed to be attributed to its lower packing factor (PF), which was caused by the CH3NH3+ vacancy (VMA) after doping This work provides a new approach to tune the band gap and charge carrier lifetime of the hybrid perovskite CH3NH3PbI3, which should be promising to further improve the performance of perovskite-based photovoltaic devices. (C) 2016 Elsevier B.V. All rights reserved.
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
研究领域[WOS]	Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
关键词[WOS]	PEROVSKITE SOLAR-CELLS ; ORGANOMETAL HALIDE PEROVSKITES ; METHYLAMMONIUM LEAD IODIDE ; FORMAMIDINIUM TIN IODIDE ; PHOTOVOLTAIC APPLICATIONS ; SINGLE-CRYSTALS ; SOLUTION GROWTH ; EFFICIENT ; PERFORMANCE ; CHLORINE
收录类别	SCI
语种	英语
WOS记录号	WOS:000391817600067
内容类型	期刊论文
源URL	[http://ir.sic.ac.cn/handle/331005/21903]
专题	上海硅酸盐研究所_能量转换材料重点实验室_期刊论文
作者单位	1.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China 3.Chinese Acad Sci, CAS Key Lab Mat Energy Convers, Shanghai Inst Ceram, Shanghai 200050, Peoples R China 4.Chinese Acad Sci, State Key Lab High Performance Ceram & Superfine, Shanghai Inst Ceram, Shanghai 200050, Peoples R China 5.State Grid Smart Grid Res Inst, State Key Lab Adv Transmiss Technol, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Wang, Ruiqi,Zhang, Xian,He, Jianqiao,et al. Bi3+-doped CH3NH3PbI3: Red-shifting absorption edge and longer charge carrier lifetime[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2017,695:555-560.
APA	Wang, Ruiqi.,Zhang, Xian.,He, Jianqiao.,Ma, Cheng.,Xu, Li.,...&Huang, Fuqiang.(2017).Bi3+-doped CH3NH3PbI3: Red-shifting absorption edge and longer charge carrier lifetime.JOURNAL OF ALLOYS AND COMPOUNDS,695,555-560.
MLA	Wang, Ruiqi,et al."Bi3+-doped CH3NH3PbI3: Red-shifting absorption edge and longer charge carrier lifetime".JOURNAL OF ALLOYS AND COMPOUNDS 695(2017):555-560.