Investigation on Quick Fabrication of n-type Filled Skutterudites
Yao Zheng1,2; Qiu Peng-Fei2; Li Xiao-Ya2; Chen Li-Dong2
刊名JOURNAL OF INORGANIC MATERIALS
2016-12-01
卷号31期号:12页码:1375-1382
关键词filled skutterudites melting-quenching/SPS microstructure thermoelectric performance
英文摘要

The cost-effective fabrication of CoSb3-based filled skutterudites (SKD) thermoelectric materials is a bottleneck issue preventing their successful commercial application. In this study, we employed a simple and scalable process to simultaneously produce a rapid formation and consolidation of n-type filled skutterudites. This method, consisting of RF-induction melting, quenching and spark plasma sintering (SPS), required less than a half-hour, significantly shorter than conventional process of furnace melting (over 24 h), annealing (about one week) and SPS. The fabricated bulk SKD materials possessed homogeneous composition and structures with a good thermoelectric performance which are analogous to those materials fabricated according to a conventional process. The homogeneous microstructures and phase composition distribution which was a result of the simultaneously proceeded rapid reaction and densification of the grinding-destructed dendrite networks of the Sb/CoSb/CoSb2 peritectic structure formed in the RF-induction melting and quenching. The good thermoelectric TE performance and the very low consumption of process time and energy would make this simple process a potential and practical method for industrial-level mass production of filled skutterudite thermoelectric materials.

WOS标题词Science & Technology ; Technology
类目[WOS]Materials Science, Ceramics
研究领域[WOS]Materials Science
关键词[WOS]THERMOELECTRIC PROPERTIES ; FUTURE CHALLENGES ; POWER-GENERATION ; PERFORMANCE ; PROGRESS ; DEVICES ; SR ; LA
收录类别SCI
语种英语
WOS记录号WOS:000389649100015
内容类型期刊论文
源URL[http://ir.sic.ac.cn/handle/331005/21935]  
专题上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文
作者单位1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
推荐引用方式
GB/T 7714
Yao Zheng,Qiu Peng-Fei,Li Xiao-Ya,et al. Investigation on Quick Fabrication of n-type Filled Skutterudites[J]. JOURNAL OF INORGANIC MATERIALS,2016,31(12):1375-1382.
APA Yao Zheng,Qiu Peng-Fei,Li Xiao-Ya,&Chen Li-Dong.(2016).Investigation on Quick Fabrication of n-type Filled Skutterudites.JOURNAL OF INORGANIC MATERIALS,31(12),1375-1382.
MLA Yao Zheng,et al."Investigation on Quick Fabrication of n-type Filled Skutterudites".JOURNAL OF INORGANIC MATERIALS 31.12(2016):1375-1382.
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