Tuning the fused aromatic rings to enhance photovoltaic performance in wide band-gap polymer solar cells

CORC > 青岛生物能源与过程研究所 > 中国科学院青岛生物能源与过程研究所 > 先进有机功能材料团队

	Tuning the fused aromatic rings to enhance photovoltaic performance in wide band-gap polymer solar cells
	Dang, Dongfeng 1,2; Chen, Jinxiang 3; Zhou, Pei 2; Duan, Linrui 2,4; Bao, Xichang 4; Yang, Renqiang 4; Chen, Junwu 3; Zhu, Weiguo 2,5
刊名	POLYMER
	2016-11-08
卷号	104 页码:130-137
关键词	Polymer solar cells Organic field-effect transistors Wide band-gap polymers
英文摘要	Two novel wide band-gap polymers of PFT1 and PFT2 were designed as the alternative to P3HT in organic electronics, in which the fused aromatic rings were utilized and altered to tune their molecular co-planarity and photovoltaic performance in solar cells. As observed, although PFT1 exhibited strong inter-molecular interaction, slightly twisted molecular structure was observed, thus leading to an inferior PCE value of 1.95% in BHJ solar cells and holes mobility of 2.04 x 10(-2) cm(2) V-1 s(-1) in OFETs in contrast to its isomeric polymer PBTFT. On the other hand, when the fused thiophene rings was tuned to construct PFT2, much planar polymer backbone was achieved, finally leading to the maximum PCE value of 3.34% in polymer solar cells and much enhanced holes mobility up to 3.93 x 10(-2) cm(2) V-1 s(-1) in OFETs. Our results here further indicated that tuning the fused aromatic rings in polymer backbone could improve their charge transfer properties and enhance their photovoltaic performance in solar cells significantly. (C) 2016 Elsevier Ltd. All rights reserved.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Polymer Science
研究领域[WOS]	Polymer Science
关键词[WOS]	POWER CONVERSION EFFICIENCY ; CONJUGATED POLYMERS ; ELECTRON-ACCEPTOR ; MOLECULAR DESIGN ; COPOLYMERS ; BENZODITHIOPHENE ; MOIETIES ; POLYAZOMETHINES ; BENZOTHIADIAZOLE ; TRANSISTORS
收录类别	SCI
语种	英语
WOS记录号	WOS:000386927700014
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/9086]
专题	青岛生物能源与过程研究所_先进有机功能材料团队
作者单位	1.Xi An Jiao Tong Univ, Sch Sci, Xian 710049, Peoples R China 2.Xiangtan Univ, Dept Chem, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Xiangtan 411105, Peoples R China 3.South China Univ Technol, Inst Polymer Optoelect Mat & Devices, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China 4.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 5.Changzhou Univ, Sch Mat Sci & Engn, Changzhou 213164, Peoples R China
推荐引用方式 GB/T 7714	Dang, Dongfeng,Chen, Jinxiang,Zhou, Pei,et al. Tuning the fused aromatic rings to enhance photovoltaic performance in wide band-gap polymer solar cells[J]. POLYMER,2016,104:130-137.
APA	Dang, Dongfeng.,Chen, Jinxiang.,Zhou, Pei.,Duan, Linrui.,Bao, Xichang.,...&Zhu, Weiguo.(2016).Tuning the fused aromatic rings to enhance photovoltaic performance in wide band-gap polymer solar cells.POLYMER,104,130-137.
MLA	Dang, Dongfeng,et al."Tuning the fused aromatic rings to enhance photovoltaic performance in wide band-gap polymer solar cells".POLYMER 104(2016):130-137.