Visible-Light-Induced Photocatalysis of 1,1,1-Trifluoro-2-iodoethane with Alkylalkenes and Silyl Enol Ethers

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	Visible-Light-Induced Photocatalysis of 1,1,1-Trifluoro-2-iodoethane with Alkylalkenes and Silyl Enol Ethers
	Huang MW(黄美薇)1; Li L(李伦)1; Zhao ZG(赵志刚)1; Chen QY(陈庆云)1; Guo Y(郭勇)1
刊名	Synthesis
	2015
卷号	47 期号:24 页码:3891-3900
其他题名	可见光促进的烯烃和烯醇硅醚与三氟碘乙烷的三氟乙基化反应
通讯作者	赵志刚 ; 陈庆云 ; 郭勇
英文摘要	Reactions of 1,1,1-trifluoro-2-iodoethane with alkylalkenes and silyl enol ethers were performed in the presence of a catalytic amount of fac-Ir(ppy)(3) and an excessive amount of Hunig's base in acetonitrile irradiated by a 24 W fluorescent lamp under nitrogen atmosphere for 48 hours. The visible-light-induced photoredox reactions introduce simultaneously a 2,2,2-trifluoroethyl group and an iodine atom to both sides of the double bond of ordinary alkenes via an atom-transfer radical addition (ATRA). The same reaction with silyl enol ethers generates -trifluoromethyl ketones, which are typically a challenge to synthesize. The reactions proved to be tolerant of a variety of functionalities.
学科主题	氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1055/s-0035-1560260
语种	英语
WOS记录号	WOS:000366209800008
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39765]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
作者单位	1.西南民族大学 2.中科院上海有机化学研究所, 有机氟化学重点实验室
推荐引用方式 GB/T 7714	Huang MW,Li L,Zhao ZG,et al. Visible-Light-Induced Photocatalysis of 1,1,1-Trifluoro-2-iodoethane with Alkylalkenes and Silyl Enol Ethers[J]. Synthesis,2015,47(24):3891-3900.
APA	黄美薇,李伦,赵志刚,陈庆云,&郭勇.(2015).Visible-Light-Induced Photocatalysis of 1,1,1-Trifluoro-2-iodoethane with Alkylalkenes and Silyl Enol Ethers.Synthesis,47(24),3891-3900.
MLA	黄美薇,et al."Visible-Light-Induced Photocatalysis of 1,1,1-Trifluoro-2-iodoethane with Alkylalkenes and Silyl Enol Ethers".Synthesis 47.24(2015):3891-3900.